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Chloridotetra­pyridine­copper(II) dicyanamidate pyridine disolvate

In the crystal structure of the title compound, [CuCl(C(5)H(5)N)(4)][N(CN)(2)]·2C(6)H(5)N, the copper(II) cations are coordinated by one chloride anion and four N-bonded pyridine ligands into discrete complexes. The copper(II) cation shows a square-pyramidal coordination environment, with the chlori...

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Autores principales: Wöhlert, Susanne, Wriedt, Mario, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120354/
https://www.ncbi.nlm.nih.gov/pubmed/21754599
http://dx.doi.org/10.1107/S1600536811016187
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author Wöhlert, Susanne
Wriedt, Mario
Jess, Inke
Näther, Christian
author_facet Wöhlert, Susanne
Wriedt, Mario
Jess, Inke
Näther, Christian
author_sort Wöhlert, Susanne
collection PubMed
description In the crystal structure of the title compound, [CuCl(C(5)H(5)N)(4)][N(CN)(2)]·2C(6)H(5)N, the copper(II) cations are coordinated by one chloride anion and four N-bonded pyridine ligands into discrete complexes. The copper(II) cation shows a square-pyramidal coordination environment, with the chloride anion in the apical position. However, there is one additional chloride anion at 3.0065 (9) Å, leading to a disorted octa­hedral coordination mode for copper. The copper(II) cation, the chloride ligand and the central N atom of the dicyanamide anion are located on twofold rotation axes. Two pyridine solvent molecules are observed in general positions.
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spelling pubmed-31203542011-07-13 Chloridotetra­pyridine­copper(II) dicyanamidate pyridine disolvate Wöhlert, Susanne Wriedt, Mario Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [CuCl(C(5)H(5)N)(4)][N(CN)(2)]·2C(6)H(5)N, the copper(II) cations are coordinated by one chloride anion and four N-bonded pyridine ligands into discrete complexes. The copper(II) cation shows a square-pyramidal coordination environment, with the chloride anion in the apical position. However, there is one additional chloride anion at 3.0065 (9) Å, leading to a disorted octa­hedral coordination mode for copper. The copper(II) cation, the chloride ligand and the central N atom of the dicyanamide anion are located on twofold rotation axes. Two pyridine solvent molecules are observed in general positions. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120354/ /pubmed/21754599 http://dx.doi.org/10.1107/S1600536811016187 Text en © Wöhlert et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wöhlert, Susanne
Wriedt, Mario
Jess, Inke
Näther, Christian
Chloridotetra­pyridine­copper(II) dicyanamidate pyridine disolvate
title Chloridotetra­pyridine­copper(II) dicyanamidate pyridine disolvate
title_full Chloridotetra­pyridine­copper(II) dicyanamidate pyridine disolvate
title_fullStr Chloridotetra­pyridine­copper(II) dicyanamidate pyridine disolvate
title_full_unstemmed Chloridotetra­pyridine­copper(II) dicyanamidate pyridine disolvate
title_short Chloridotetra­pyridine­copper(II) dicyanamidate pyridine disolvate
title_sort chloridotetra­pyridine­copper(ii) dicyanamidate pyridine disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120354/
https://www.ncbi.nlm.nih.gov/pubmed/21754599
http://dx.doi.org/10.1107/S1600536811016187
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