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Chloridotetrapyridinecopper(II) dicyanamidate pyridine disolvate
In the crystal structure of the title compound, [CuCl(C(5)H(5)N)(4)][N(CN)(2)]·2C(6)H(5)N, the copper(II) cations are coordinated by one chloride anion and four N-bonded pyridine ligands into discrete complexes. The copper(II) cation shows a square-pyramidal coordination environment, with the chlori...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120354/ https://www.ncbi.nlm.nih.gov/pubmed/21754599 http://dx.doi.org/10.1107/S1600536811016187 |
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author | Wöhlert, Susanne Wriedt, Mario Jess, Inke Näther, Christian |
author_facet | Wöhlert, Susanne Wriedt, Mario Jess, Inke Näther, Christian |
author_sort | Wöhlert, Susanne |
collection | PubMed |
description | In the crystal structure of the title compound, [CuCl(C(5)H(5)N)(4)][N(CN)(2)]·2C(6)H(5)N, the copper(II) cations are coordinated by one chloride anion and four N-bonded pyridine ligands into discrete complexes. The copper(II) cation shows a square-pyramidal coordination environment, with the chloride anion in the apical position. However, there is one additional chloride anion at 3.0065 (9) Å, leading to a disorted octahedral coordination mode for copper. The copper(II) cation, the chloride ligand and the central N atom of the dicyanamide anion are located on twofold rotation axes. Two pyridine solvent molecules are observed in general positions. |
format | Online Article Text |
id | pubmed-3120354 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31203542011-07-13 Chloridotetrapyridinecopper(II) dicyanamidate pyridine disolvate Wöhlert, Susanne Wriedt, Mario Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [CuCl(C(5)H(5)N)(4)][N(CN)(2)]·2C(6)H(5)N, the copper(II) cations are coordinated by one chloride anion and four N-bonded pyridine ligands into discrete complexes. The copper(II) cation shows a square-pyramidal coordination environment, with the chloride anion in the apical position. However, there is one additional chloride anion at 3.0065 (9) Å, leading to a disorted octahedral coordination mode for copper. The copper(II) cation, the chloride ligand and the central N atom of the dicyanamide anion are located on twofold rotation axes. Two pyridine solvent molecules are observed in general positions. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120354/ /pubmed/21754599 http://dx.doi.org/10.1107/S1600536811016187 Text en © Wöhlert et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wöhlert, Susanne Wriedt, Mario Jess, Inke Näther, Christian Chloridotetrapyridinecopper(II) dicyanamidate pyridine disolvate |
title | Chloridotetrapyridinecopper(II) dicyanamidate pyridine disolvate |
title_full | Chloridotetrapyridinecopper(II) dicyanamidate pyridine disolvate |
title_fullStr | Chloridotetrapyridinecopper(II) dicyanamidate pyridine disolvate |
title_full_unstemmed | Chloridotetrapyridinecopper(II) dicyanamidate pyridine disolvate |
title_short | Chloridotetrapyridinecopper(II) dicyanamidate pyridine disolvate |
title_sort | chloridotetrapyridinecopper(ii) dicyanamidate pyridine disolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120354/ https://www.ncbi.nlm.nih.gov/pubmed/21754599 http://dx.doi.org/10.1107/S1600536811016187 |
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