catena-Poly[[bis(pyridine)­lead(II)]bis(μ-penta­fluoro­benzene­thiol­ato)]

The title compound, [Pb(C(6)F(5)S)(2)(C(5)H(5)N)(2)](n), shows the Pb(II) atom in a ψ-trigonal bipyramidal S(2)N(2) bonding environment. Pyridine N atoms occupy axial sites, while thiol­ate S atoms and a stereochemically active lone pair occupy equatorial sites. Very long inter­molecular Pb⋯S inter­...

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Detalles Bibliográficos
Autores principales: Appleton, Sarah E., Briand, Glen G., Decken, Andreas, Smith, Anita S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120355/
https://www.ncbi.nlm.nih.gov/pubmed/21754614
http://dx.doi.org/10.1107/S160053681101659X
Descripción
Sumario:The title compound, [Pb(C(6)F(5)S)(2)(C(5)H(5)N)(2)](n), shows the Pb(II) atom in a ψ-trigonal bipyramidal S(2)N(2) bonding environment. Pyridine N atoms occupy axial sites, while thiol­ate S atoms and a stereochemically active lone pair occupy equatorial sites. Very long inter­molecular Pb⋯S inter­actions [3.618 (4) and 3.614 (4) Å] yield a weakly associated one-dimensional polymeric structure extending parallel to [010].

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