catena-Poly[[bis(pyridine)­lead(II)]bis(μ-penta­fluoro­benzene­thiol­ato)]

The title compound, [Pb(C(6)F(5)S)(2)(C(5)H(5)N)(2)](n), shows the Pb(II) atom in a ψ-trigonal bipyramidal S(2)N(2) bonding environment. Pyridine N atoms occupy axial sites, while thiol­ate S atoms and a stereochemically active lone pair occupy equatorial sites. Very long inter­molecular Pb⋯S inter­...

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Detalles Bibliográficos
Autores principales: Appleton, Sarah E., Briand, Glen G., Decken, Andreas, Smith, Anita S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120355/
https://www.ncbi.nlm.nih.gov/pubmed/21754614
http://dx.doi.org/10.1107/S160053681101659X
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author Appleton, Sarah E.
Briand, Glen G.
Decken, Andreas
Smith, Anita S.
author_facet Appleton, Sarah E.
Briand, Glen G.
Decken, Andreas
Smith, Anita S.
author_sort Appleton, Sarah E.
collection PubMed
description The title compound, [Pb(C(6)F(5)S)(2)(C(5)H(5)N)(2)](n), shows the Pb(II) atom in a ψ-trigonal bipyramidal S(2)N(2) bonding environment. Pyridine N atoms occupy axial sites, while thiol­ate S atoms and a stereochemically active lone pair occupy equatorial sites. Very long inter­molecular Pb⋯S inter­actions [3.618 (4) and 3.614 (4) Å] yield a weakly associated one-dimensional polymeric structure extending parallel to [010].
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spelling pubmed-31203552011-07-13 catena-Poly[[bis(pyridine)­lead(II)]bis(μ-penta­fluoro­benzene­thiol­ato)] Appleton, Sarah E. Briand, Glen G. Decken, Andreas Smith, Anita S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Pb(C(6)F(5)S)(2)(C(5)H(5)N)(2)](n), shows the Pb(II) atom in a ψ-trigonal bipyramidal S(2)N(2) bonding environment. Pyridine N atoms occupy axial sites, while thiol­ate S atoms and a stereochemically active lone pair occupy equatorial sites. Very long inter­molecular Pb⋯S inter­actions [3.618 (4) and 3.614 (4) Å] yield a weakly associated one-dimensional polymeric structure extending parallel to [010]. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120355/ /pubmed/21754614 http://dx.doi.org/10.1107/S160053681101659X Text en © Appleton et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Appleton, Sarah E.
Briand, Glen G.
Decken, Andreas
Smith, Anita S.
catena-Poly[[bis(pyridine)­lead(II)]bis(μ-penta­fluoro­benzene­thiol­ato)]
title catena-Poly[[bis(pyridine)­lead(II)]bis(μ-penta­fluoro­benzene­thiol­ato)]
title_full catena-Poly[[bis(pyridine)­lead(II)]bis(μ-penta­fluoro­benzene­thiol­ato)]
title_fullStr catena-Poly[[bis(pyridine)­lead(II)]bis(μ-penta­fluoro­benzene­thiol­ato)]
title_full_unstemmed catena-Poly[[bis(pyridine)­lead(II)]bis(μ-penta­fluoro­benzene­thiol­ato)]
title_short catena-Poly[[bis(pyridine)­lead(II)]bis(μ-penta­fluoro­benzene­thiol­ato)]
title_sort catena-poly[[bis(pyridine)­lead(ii)]bis(μ-penta­fluoro­benzene­thiol­ato)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120355/
https://www.ncbi.nlm.nih.gov/pubmed/21754614
http://dx.doi.org/10.1107/S160053681101659X
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