Tetra­aqua­bis­[2-(4-pyridyl­sulfan­yl)acetato-κN]nickel(II)

In the centrosymmetric title complex, [Ni(C(7)H(6)NO(2)S)(2)(H(2)O)(4)], the Ni(II) atom, located on a centre of inversion, is coordinated by two N atoms from two 2-(4-pyridyl­sulfan­yl)acetate ligands and four water O atoms in an octa­hedral geometry. In the crystal, inter­molecular O—H⋯O hydrogen...

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Detalles Bibliográficos
Autores principales: Wang, Jing-Yi, Wang, Xiu-Guang, Zhao, Xiao-Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120356/
https://www.ncbi.nlm.nih.gov/pubmed/21754673
http://dx.doi.org/10.1107/S1600536811019131
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author Wang, Jing-Yi
Wang, Xiu-Guang
Zhao, Xiao-Jun
author_facet Wang, Jing-Yi
Wang, Xiu-Guang
Zhao, Xiao-Jun
author_sort Wang, Jing-Yi
collection PubMed
description In the centrosymmetric title complex, [Ni(C(7)H(6)NO(2)S)(2)(H(2)O)(4)], the Ni(II) atom, located on a centre of inversion, is coordinated by two N atoms from two 2-(4-pyridyl­sulfan­yl)acetate ligands and four water O atoms in an octa­hedral geometry. In the crystal, inter­molecular O—H⋯O hydrogen bonds between the coordinated water mol­ecules and the carboxyl­ate group of the anionic 2-(4-pyridyl­sulfan­yl)acetate ligands link these discrete mononuclear units into a three-dimensional network.
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spelling pubmed-31203562011-07-13 Tetra­aqua­bis­[2-(4-pyridyl­sulfan­yl)acetato-κN]nickel(II) Wang, Jing-Yi Wang, Xiu-Guang Zhao, Xiao-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric title complex, [Ni(C(7)H(6)NO(2)S)(2)(H(2)O)(4)], the Ni(II) atom, located on a centre of inversion, is coordinated by two N atoms from two 2-(4-pyridyl­sulfan­yl)acetate ligands and four water O atoms in an octa­hedral geometry. In the crystal, inter­molecular O—H⋯O hydrogen bonds between the coordinated water mol­ecules and the carboxyl­ate group of the anionic 2-(4-pyridyl­sulfan­yl)acetate ligands link these discrete mononuclear units into a three-dimensional network. International Union of Crystallography 2011-05-25 /pmc/articles/PMC3120356/ /pubmed/21754673 http://dx.doi.org/10.1107/S1600536811019131 Text en © Wang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Jing-Yi
Wang, Xiu-Guang
Zhao, Xiao-Jun
Tetra­aqua­bis­[2-(4-pyridyl­sulfan­yl)acetato-κN]nickel(II)
title Tetra­aqua­bis­[2-(4-pyridyl­sulfan­yl)acetato-κN]nickel(II)
title_full Tetra­aqua­bis­[2-(4-pyridyl­sulfan­yl)acetato-κN]nickel(II)
title_fullStr Tetra­aqua­bis­[2-(4-pyridyl­sulfan­yl)acetato-κN]nickel(II)
title_full_unstemmed Tetra­aqua­bis­[2-(4-pyridyl­sulfan­yl)acetato-κN]nickel(II)
title_short Tetra­aqua­bis­[2-(4-pyridyl­sulfan­yl)acetato-κN]nickel(II)
title_sort tetra­aqua­bis­[2-(4-pyridyl­sulfan­yl)acetato-κn]nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120356/
https://www.ncbi.nlm.nih.gov/pubmed/21754673
http://dx.doi.org/10.1107/S1600536811019131
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