Bis(dimethyl­ammonium) tetra­chlorido­dimethyl­stannate(IV)

Regular crystals of the title compound, (C(2)H(8)N)(2)[Sn(CH(3))(2)Cl(4)], were obtained by reacting SnMe(2)Cl(2) with (CH(3))(2)NH·HCl in ethanol in a 1:1 ratio. The Sn atom lies on a center of symmetry and is six-coordinated. It has a distorted octahedral SnC(2)Cl(4) environment with the Cl atoms...

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Detalles Bibliográficos
Autores principales: Diop, Tidiane, Diop, Libasse, Michaud, Francois
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120357/
https://www.ncbi.nlm.nih.gov/pubmed/21754600
http://dx.doi.org/10.1107/S1600536811013584
Descripción
Sumario:Regular crystals of the title compound, (C(2)H(8)N)(2)[Sn(CH(3))(2)Cl(4)], were obtained by reacting SnMe(2)Cl(2) with (CH(3))(2)NH·HCl in ethanol in a 1:1 ratio. The Sn atom lies on a center of symmetry and is six-coordinated. It has a distorted octahedral SnC(2)Cl(4) environment with the Cl atoms in cis positions. The Cl atoms are connected to dimethyl­ammonium cations through N—H⋯Cl hydrogen bonds, forming an infinite chain extending parallel to [010].

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