Bis(dimethyl­ammonium) tetra­chlorido­dimethyl­stannate(IV)

Regular crystals of the title compound, (C(2)H(8)N)(2)[Sn(CH(3))(2)Cl(4)], were obtained by reacting SnMe(2)Cl(2) with (CH(3))(2)NH·HCl in ethanol in a 1:1 ratio. The Sn atom lies on a center of symmetry and is six-coordinated. It has a distorted octahedral SnC(2)Cl(4) environment with the Cl atoms...

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Detalles Bibliográficos
Autores principales: Diop, Tidiane, Diop, Libasse, Michaud, Francois
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120357/
https://www.ncbi.nlm.nih.gov/pubmed/21754600
http://dx.doi.org/10.1107/S1600536811013584
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author Diop, Tidiane
Diop, Libasse
Michaud, Francois
author_facet Diop, Tidiane
Diop, Libasse
Michaud, Francois
author_sort Diop, Tidiane
collection PubMed
description Regular crystals of the title compound, (C(2)H(8)N)(2)[Sn(CH(3))(2)Cl(4)], were obtained by reacting SnMe(2)Cl(2) with (CH(3))(2)NH·HCl in ethanol in a 1:1 ratio. The Sn atom lies on a center of symmetry and is six-coordinated. It has a distorted octahedral SnC(2)Cl(4) environment with the Cl atoms in cis positions. The Cl atoms are connected to dimethyl­ammonium cations through N—H⋯Cl hydrogen bonds, forming an infinite chain extending parallel to [010].
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spelling pubmed-31203572011-07-13 Bis(dimethyl­ammonium) tetra­chlorido­dimethyl­stannate(IV) Diop, Tidiane Diop, Libasse Michaud, Francois Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Regular crystals of the title compound, (C(2)H(8)N)(2)[Sn(CH(3))(2)Cl(4)], were obtained by reacting SnMe(2)Cl(2) with (CH(3))(2)NH·HCl in ethanol in a 1:1 ratio. The Sn atom lies on a center of symmetry and is six-coordinated. It has a distorted octahedral SnC(2)Cl(4) environment with the Cl atoms in cis positions. The Cl atoms are connected to dimethyl­ammonium cations through N—H⋯Cl hydrogen bonds, forming an infinite chain extending parallel to [010]. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120357/ /pubmed/21754600 http://dx.doi.org/10.1107/S1600536811013584 Text en © Diop et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Diop, Tidiane
Diop, Libasse
Michaud, Francois
Bis(dimethyl­ammonium) tetra­chlorido­dimethyl­stannate(IV)
title Bis(dimethyl­ammonium) tetra­chlorido­dimethyl­stannate(IV)
title_full Bis(dimethyl­ammonium) tetra­chlorido­dimethyl­stannate(IV)
title_fullStr Bis(dimethyl­ammonium) tetra­chlorido­dimethyl­stannate(IV)
title_full_unstemmed Bis(dimethyl­ammonium) tetra­chlorido­dimethyl­stannate(IV)
title_short Bis(dimethyl­ammonium) tetra­chlorido­dimethyl­stannate(IV)
title_sort bis(dimethyl­ammonium) tetra­chlorido­dimethyl­stannate(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120357/
https://www.ncbi.nlm.nih.gov/pubmed/21754600
http://dx.doi.org/10.1107/S1600536811013584
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AT dioplibasse bisdimethylammoniumtetrachloridodimethylstannateiv
AT michaudfrancois bisdimethylammoniumtetrachloridodimethylstannateiv

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