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N,N,N′,N′-Tetrakis(2-hydroxy-5-methylbenzyl)ethane-1,2-diamine dimethylformamide disolvate
The title compound, C(34)H(40)N(2)O(4)·2C(3)H(7)NO, was synthesized by the Mannich condensation of ethanediamine, formaldehyde and p-cresol. In the crystal, the tetraphenol molecule is arranged around an inversion center. The molecule and the dimethylformamide solvate are linked through an O—H⋯...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120359/ https://www.ncbi.nlm.nih.gov/pubmed/21754816 http://dx.doi.org/10.1107/S1600536811017934 |
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author | Wang, Nuan-Sheng Wang, Yong-Tao Guo, Xiu-Kai Li, Tian-Duo |
author_facet | Wang, Nuan-Sheng Wang, Yong-Tao Guo, Xiu-Kai Li, Tian-Duo |
author_sort | Wang, Nuan-Sheng |
collection | PubMed |
description | The title compound, C(34)H(40)N(2)O(4)·2C(3)H(7)NO, was synthesized by the Mannich condensation of ethanediamine, formaldehyde and p-cresol. In the crystal, the tetraphenol molecule is arranged around an inversion center. The molecule and the dimethylformamide solvate are linked through an O—H⋯O hydrogen bond. An intramolecular O—H⋯N hydrogen bond occurs in the tetraphenol molecule, which may influence the molecular confomation. Futhermore, C—H⋯O and π–π stacking interactions [centroid–centroid distance = 3.7081 (14) Å] stabilize the crystal packing, building a three-dimensional network. |
format | Online Article Text |
id | pubmed-3120359 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31203592011-07-13 N,N,N′,N′-Tetrakis(2-hydroxy-5-methylbenzyl)ethane-1,2-diamine dimethylformamide disolvate Wang, Nuan-Sheng Wang, Yong-Tao Guo, Xiu-Kai Li, Tian-Duo Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(34)H(40)N(2)O(4)·2C(3)H(7)NO, was synthesized by the Mannich condensation of ethanediamine, formaldehyde and p-cresol. In the crystal, the tetraphenol molecule is arranged around an inversion center. The molecule and the dimethylformamide solvate are linked through an O—H⋯O hydrogen bond. An intramolecular O—H⋯N hydrogen bond occurs in the tetraphenol molecule, which may influence the molecular confomation. Futhermore, C—H⋯O and π–π stacking interactions [centroid–centroid distance = 3.7081 (14) Å] stabilize the crystal packing, building a three-dimensional network. International Union of Crystallography 2011-05-20 /pmc/articles/PMC3120359/ /pubmed/21754816 http://dx.doi.org/10.1107/S1600536811017934 Text en © Wang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Wang, Nuan-Sheng Wang, Yong-Tao Guo, Xiu-Kai Li, Tian-Duo N,N,N′,N′-Tetrakis(2-hydroxy-5-methylbenzyl)ethane-1,2-diamine dimethylformamide disolvate |
title |
N,N,N′,N′-Tetrakis(2-hydroxy-5-methylbenzyl)ethane-1,2-diamine dimethylformamide disolvate |
title_full |
N,N,N′,N′-Tetrakis(2-hydroxy-5-methylbenzyl)ethane-1,2-diamine dimethylformamide disolvate |
title_fullStr |
N,N,N′,N′-Tetrakis(2-hydroxy-5-methylbenzyl)ethane-1,2-diamine dimethylformamide disolvate |
title_full_unstemmed |
N,N,N′,N′-Tetrakis(2-hydroxy-5-methylbenzyl)ethane-1,2-diamine dimethylformamide disolvate |
title_short |
N,N,N′,N′-Tetrakis(2-hydroxy-5-methylbenzyl)ethane-1,2-diamine dimethylformamide disolvate |
title_sort | n,n,n′,n′-tetrakis(2-hydroxy-5-methylbenzyl)ethane-1,2-diamine dimethylformamide disolvate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120359/ https://www.ncbi.nlm.nih.gov/pubmed/21754816 http://dx.doi.org/10.1107/S1600536811017934 |
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