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N,N,N′,N′-Tetra­kis(2-hy­droxy-5-methyl­benz­yl)ethane-1,2-diamine dimethyl­formamide disolvate

The title compound, C(34)H(40)N(2)O(4)·2C(3)H(7)NO, was synthesized by the Mannich condensation of ethane­diamine, formaldehyde and p-cresol. In the crystal, the tetra­phenol mol­ecule is arranged around an inversion center. The mol­ecule and the dimethyl­formamide solvate are linked through an O—H⋯...

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Autores principales: Wang, Nuan-Sheng, Wang, Yong-Tao, Guo, Xiu-Kai, Li, Tian-Duo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120359/
https://www.ncbi.nlm.nih.gov/pubmed/21754816
http://dx.doi.org/10.1107/S1600536811017934
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author Wang, Nuan-Sheng
Wang, Yong-Tao
Guo, Xiu-Kai
Li, Tian-Duo
author_facet Wang, Nuan-Sheng
Wang, Yong-Tao
Guo, Xiu-Kai
Li, Tian-Duo
author_sort Wang, Nuan-Sheng
collection PubMed
description The title compound, C(34)H(40)N(2)O(4)·2C(3)H(7)NO, was synthesized by the Mannich condensation of ethane­diamine, formaldehyde and p-cresol. In the crystal, the tetra­phenol mol­ecule is arranged around an inversion center. The mol­ecule and the dimethyl­formamide solvate are linked through an O—H⋯O hydrogen bond. An intra­molecular O—H⋯N hydrogen bond occurs in the tetra­phenol mol­ecule, which may influence the mol­ecular confomation. Futhermore, C—H⋯O and π–π stacking inter­actions [centroid–centroid distance = 3.7081 (14) Å] stabilize the crystal packing, building a three-dimensional network.
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spelling pubmed-31203592011-07-13 N,N,N′,N′-Tetra­kis(2-hy­droxy-5-methyl­benz­yl)ethane-1,2-diamine dimethyl­formamide disolvate Wang, Nuan-Sheng Wang, Yong-Tao Guo, Xiu-Kai Li, Tian-Duo Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(34)H(40)N(2)O(4)·2C(3)H(7)NO, was synthesized by the Mannich condensation of ethane­diamine, formaldehyde and p-cresol. In the crystal, the tetra­phenol mol­ecule is arranged around an inversion center. The mol­ecule and the dimethyl­formamide solvate are linked through an O—H⋯O hydrogen bond. An intra­molecular O—H⋯N hydrogen bond occurs in the tetra­phenol mol­ecule, which may influence the mol­ecular confomation. Futhermore, C—H⋯O and π–π stacking inter­actions [centroid–centroid distance = 3.7081 (14) Å] stabilize the crystal packing, building a three-dimensional network. International Union of Crystallography 2011-05-20 /pmc/articles/PMC3120359/ /pubmed/21754816 http://dx.doi.org/10.1107/S1600536811017934 Text en © Wang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wang, Nuan-Sheng
Wang, Yong-Tao
Guo, Xiu-Kai
Li, Tian-Duo
N,N,N′,N′-Tetra­kis(2-hy­droxy-5-methyl­benz­yl)ethane-1,2-diamine dimethyl­formamide disolvate
title N,N,N′,N′-Tetra­kis(2-hy­droxy-5-methyl­benz­yl)ethane-1,2-diamine dimethyl­formamide disolvate
title_full N,N,N′,N′-Tetra­kis(2-hy­droxy-5-methyl­benz­yl)ethane-1,2-diamine dimethyl­formamide disolvate
title_fullStr N,N,N′,N′-Tetra­kis(2-hy­droxy-5-methyl­benz­yl)ethane-1,2-diamine dimethyl­formamide disolvate
title_full_unstemmed N,N,N′,N′-Tetra­kis(2-hy­droxy-5-methyl­benz­yl)ethane-1,2-diamine dimethyl­formamide disolvate
title_short N,N,N′,N′-Tetra­kis(2-hy­droxy-5-methyl­benz­yl)ethane-1,2-diamine dimethyl­formamide disolvate
title_sort n,n,n′,n′-tetra­kis(2-hy­droxy-5-methyl­benz­yl)ethane-1,2-diamine dimethyl­formamide disolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120359/
https://www.ncbi.nlm.nih.gov/pubmed/21754816
http://dx.doi.org/10.1107/S1600536811017934
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