N (6)-(4-Fluoro­benz­yl)-3-nitro­pyridine-2,6-diamine

In the title compound, C(12)H(11)FN(4)O(2), the pyridine ring is connected to a benzene ring by a –CH(2)—NH(2)- chain. The nitro group is twisted out of the pyridine ring plane [torsion angle O—N—C—C = 10.41 (10)°]. An intramolecular N—H⋯O hydrogen bond occurs. The fluoro­benzene ring is disordered...

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Detalles Bibliográficos
Autores principales: Ge, Ji-long, Qian, Xiao-min
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120364/
https://www.ncbi.nlm.nih.gov/pubmed/21754850
http://dx.doi.org/10.1107/S1600536811018642
Descripción
Sumario:In the title compound, C(12)H(11)FN(4)O(2), the pyridine ring is connected to a benzene ring by a –CH(2)—NH(2)- chain. The nitro group is twisted out of the pyridine ring plane [torsion angle O—N—C—C = 10.41 (10)°]. An intramolecular N—H⋯O hydrogen bond occurs. The fluoro­benzene ring is disordered over two positions [occupancy ratio = 0.59 (3):0.41 (3)]. Inter­molecular N—H⋯O and N—H⋯N hydrogen bonds stabilize the crystal structure.

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