N (6)-(4-Fluoro­benz­yl)-3-nitro­pyridine-2,6-diamine

In the title compound, C(12)H(11)FN(4)O(2), the pyridine ring is connected to a benzene ring by a –CH(2)—NH(2)- chain. The nitro group is twisted out of the pyridine ring plane [torsion angle O—N—C—C = 10.41 (10)°]. An intramolecular N—H⋯O hydrogen bond occurs. The fluoro­benzene ring is disordered...

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Detalles Bibliográficos
Autores principales: Ge, Ji-long, Qian, Xiao-min
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120364/
https://www.ncbi.nlm.nih.gov/pubmed/21754850
http://dx.doi.org/10.1107/S1600536811018642
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author Ge, Ji-long
Qian, Xiao-min
author_facet Ge, Ji-long
Qian, Xiao-min
author_sort Ge, Ji-long
collection PubMed
description In the title compound, C(12)H(11)FN(4)O(2), the pyridine ring is connected to a benzene ring by a –CH(2)—NH(2)- chain. The nitro group is twisted out of the pyridine ring plane [torsion angle O—N—C—C = 10.41 (10)°]. An intramolecular N—H⋯O hydrogen bond occurs. The fluoro­benzene ring is disordered over two positions [occupancy ratio = 0.59 (3):0.41 (3)]. Inter­molecular N—H⋯O and N—H⋯N hydrogen bonds stabilize the crystal structure.
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spelling pubmed-31203642011-07-13 N (6)-(4-Fluoro­benz­yl)-3-nitro­pyridine-2,6-diamine Ge, Ji-long Qian, Xiao-min Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(11)FN(4)O(2), the pyridine ring is connected to a benzene ring by a –CH(2)—NH(2)- chain. The nitro group is twisted out of the pyridine ring plane [torsion angle O—N—C—C = 10.41 (10)°]. An intramolecular N—H⋯O hydrogen bond occurs. The fluoro­benzene ring is disordered over two positions [occupancy ratio = 0.59 (3):0.41 (3)]. Inter­molecular N—H⋯O and N—H⋯N hydrogen bonds stabilize the crystal structure. International Union of Crystallography 2011-05-20 /pmc/articles/PMC3120364/ /pubmed/21754850 http://dx.doi.org/10.1107/S1600536811018642 Text en © Ge and Qian 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ge, Ji-long
Qian, Xiao-min
N (6)-(4-Fluoro­benz­yl)-3-nitro­pyridine-2,6-diamine
title N (6)-(4-Fluoro­benz­yl)-3-nitro­pyridine-2,6-diamine
title_full N (6)-(4-Fluoro­benz­yl)-3-nitro­pyridine-2,6-diamine
title_fullStr N (6)-(4-Fluoro­benz­yl)-3-nitro­pyridine-2,6-diamine
title_full_unstemmed N (6)-(4-Fluoro­benz­yl)-3-nitro­pyridine-2,6-diamine
title_short N (6)-(4-Fluoro­benz­yl)-3-nitro­pyridine-2,6-diamine
title_sort n (6)-(4-fluoro­benz­yl)-3-nitro­pyridine-2,6-diamine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120364/
https://www.ncbi.nlm.nih.gov/pubmed/21754850
http://dx.doi.org/10.1107/S1600536811018642
work_keys_str_mv AT gejilong n64fluorobenzyl3nitropyridine26diamine
AT qianxiaomin n64fluorobenzyl3nitropyridine26diamine

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