Bis{μ-2-[(pyridin-2-yl)imino­meth­yl]phenolato}bis­[(2-formyl­phenolato)copper(II)]

The asymmetric unit of the title compound, [Cu(2)(C(12)H(9)N(2)O)(2)(C(7)H(5)O(2))(2)], contains two independent (2-formyl­phen­olato){2-[(pyridin-2-yl)imino­meth­yl]phenolato}copper(II) mol­ecules that form pseudocentrosymmetric dimers via inter­actions between the Cu and pyridyl N atoms of indepen...

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Detalles Bibliográficos
Autores principales: Chang, Hui-Chang, Cole, Jacqueline M., Lin, Tze-Chia, Sylvester, Sven O., Waddell, Paul G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120375/
https://www.ncbi.nlm.nih.gov/pubmed/21754595
http://dx.doi.org/10.1107/S1600536811015674
Descripción
Sumario:The asymmetric unit of the title compound, [Cu(2)(C(12)H(9)N(2)O)(2)(C(7)H(5)O(2))(2)], contains two independent (2-formyl­phen­olato){2-[(pyridin-2-yl)imino­meth­yl]phenolato}copper(II) mol­ecules that form pseudocentrosymmetric dimers via inter­actions between the Cu and pyridyl N atoms of independent monomers. The square-planar geometry of the Cu atoms in the monomer thus becomes square-based pyramidal in the dimer. The crystal studied was an inversion twin, with unequal populations of 0.353 (17) and 0.647 (17).

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