Bis{μ-2-[(pyridin-2-yl)imino­meth­yl]phenolato}bis­[(2-formyl­phenolato)copper(II)]

The asymmetric unit of the title compound, [Cu(2)(C(12)H(9)N(2)O)(2)(C(7)H(5)O(2))(2)], contains two independent (2-formyl­phen­olato){2-[(pyridin-2-yl)imino­meth­yl]phenolato}copper(II) mol­ecules that form pseudocentrosymmetric dimers via inter­actions between the Cu and pyridyl N atoms of indepen...

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Autores principales: Chang, Hui-Chang, Cole, Jacqueline M., Lin, Tze-Chia, Sylvester, Sven O., Waddell, Paul G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120375/
https://www.ncbi.nlm.nih.gov/pubmed/21754595
http://dx.doi.org/10.1107/S1600536811015674
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author Chang, Hui-Chang
Cole, Jacqueline M.
Lin, Tze-Chia
Sylvester, Sven O.
Waddell, Paul G.
author_facet Chang, Hui-Chang
Cole, Jacqueline M.
Lin, Tze-Chia
Sylvester, Sven O.
Waddell, Paul G.
author_sort Chang, Hui-Chang
collection PubMed
description The asymmetric unit of the title compound, [Cu(2)(C(12)H(9)N(2)O)(2)(C(7)H(5)O(2))(2)], contains two independent (2-formyl­phen­olato){2-[(pyridin-2-yl)imino­meth­yl]phenolato}copper(II) mol­ecules that form pseudocentrosymmetric dimers via inter­actions between the Cu and pyridyl N atoms of independent monomers. The square-planar geometry of the Cu atoms in the monomer thus becomes square-based pyramidal in the dimer. The crystal studied was an inversion twin, with unequal populations of 0.353 (17) and 0.647 (17).
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spelling pubmed-31203752011-07-13 Bis{μ-2-[(pyridin-2-yl)imino­meth­yl]phenolato}bis­[(2-formyl­phenolato)copper(II)] Chang, Hui-Chang Cole, Jacqueline M. Lin, Tze-Chia Sylvester, Sven O. Waddell, Paul G. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Cu(2)(C(12)H(9)N(2)O)(2)(C(7)H(5)O(2))(2)], contains two independent (2-formyl­phen­olato){2-[(pyridin-2-yl)imino­meth­yl]phenolato}copper(II) mol­ecules that form pseudocentrosymmetric dimers via inter­actions between the Cu and pyridyl N atoms of independent monomers. The square-planar geometry of the Cu atoms in the monomer thus becomes square-based pyramidal in the dimer. The crystal studied was an inversion twin, with unequal populations of 0.353 (17) and 0.647 (17). International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120375/ /pubmed/21754595 http://dx.doi.org/10.1107/S1600536811015674 Text en © Chang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chang, Hui-Chang
Cole, Jacqueline M.
Lin, Tze-Chia
Sylvester, Sven O.
Waddell, Paul G.
Bis{μ-2-[(pyridin-2-yl)imino­meth­yl]phenolato}bis­[(2-formyl­phenolato)copper(II)]
title Bis{μ-2-[(pyridin-2-yl)imino­meth­yl]phenolato}bis­[(2-formyl­phenolato)copper(II)]
title_full Bis{μ-2-[(pyridin-2-yl)imino­meth­yl]phenolato}bis­[(2-formyl­phenolato)copper(II)]
title_fullStr Bis{μ-2-[(pyridin-2-yl)imino­meth­yl]phenolato}bis­[(2-formyl­phenolato)copper(II)]
title_full_unstemmed Bis{μ-2-[(pyridin-2-yl)imino­meth­yl]phenolato}bis­[(2-formyl­phenolato)copper(II)]
title_short Bis{μ-2-[(pyridin-2-yl)imino­meth­yl]phenolato}bis­[(2-formyl­phenolato)copper(II)]
title_sort bis{μ-2-[(pyridin-2-yl)imino­meth­yl]phenolato}bis­[(2-formyl­phenolato)copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120375/
https://www.ncbi.nlm.nih.gov/pubmed/21754595
http://dx.doi.org/10.1107/S1600536811015674
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