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Chloridotris(3,5-dimethyl-1H-pyrazole-κN (2))(formato-κO)copper(II)–dichloridobis(3,5-dimethyl-1H-pyrazole-κN (2))copper(II) (2/1)
The asymmetric unit of the title compound, [Cu(CHO(2))Cl(C(5)H(8)N(2))(3)](2)·[CuCl(2)(C(5)H(8)N(2))(2)] or 2[A]·[B], contains one A molecule and one half-molecule of B, located on a centre of inversion. The Cu(II) environments in A and B are different. In A, the Cu(II) atom is coordinated by three...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120383/ https://www.ncbi.nlm.nih.gov/pubmed/21754628 http://dx.doi.org/10.1107/S1600536811016461 |
Sumario: | The asymmetric unit of the title compound, [Cu(CHO(2))Cl(C(5)H(8)N(2))(3)](2)·[CuCl(2)(C(5)H(8)N(2))(2)] or 2[A]·[B], contains one A molecule and one half-molecule of B, located on a centre of inversion. The Cu(II) environments in A and B are different. In A, the Cu(II) atom is coordinated by three N atoms from three 3,5-dimethyl-1H-pyrazole (L) ligands, one O atom from a formate ligand and a chloride anion in an axial position [Cu—Cl = 2.4275 (7) Å] in a distorted tetragonal–pyramidal geometry. The Cu(II) atom in B is coordinated by two N atoms from two L ligands and two chloride anions [Cu—Cl = 2.2524 (6) Å] in a distorted square-planar geometry. In the crystal, intermolecular N—H⋯O hydrogen bonds link molecules A into centrosymmetric dimers. Intermolecular N—H⋯Cl hydrogen bonds further link these dimers with the B molecules, forming chains propagating in [101]. |
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