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Chloridotris(3,5-dimethyl-1H-pyrazole-κN (2))(formato-κO)copper(II)–dichlorido­bis(3,5-dimethyl-1H-pyrazole-κN (2))copper(II) (2/1)

The asymmetric unit of the title compound, [Cu(CHO(2))Cl(C(5)H(8)N(2))(3)](2)·[CuCl(2)(C(5)H(8)N(2))(2)] or 2[A]·[B], contains one A mol­ecule and one half-molecule of B, located on a centre of inversion. The Cu(II) environments in A and B are different. In A, the Cu(II) atom is coordinated by three...

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Autores principales: Davydenko, Yuliya M., Fritsky, Igor O., Pavlenko, Vadim O., Meyer, Franc, Dechert, Sebastian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120383/
https://www.ncbi.nlm.nih.gov/pubmed/21754628
http://dx.doi.org/10.1107/S1600536811016461
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author Davydenko, Yuliya M.
Fritsky, Igor O.
Pavlenko, Vadim O.
Meyer, Franc
Dechert, Sebastian
author_facet Davydenko, Yuliya M.
Fritsky, Igor O.
Pavlenko, Vadim O.
Meyer, Franc
Dechert, Sebastian
author_sort Davydenko, Yuliya M.
collection PubMed
description The asymmetric unit of the title compound, [Cu(CHO(2))Cl(C(5)H(8)N(2))(3)](2)·[CuCl(2)(C(5)H(8)N(2))(2)] or 2[A]·[B], contains one A mol­ecule and one half-molecule of B, located on a centre of inversion. The Cu(II) environments in A and B are different. In A, the Cu(II) atom is coordinated by three N atoms from three 3,5-dimethyl-1H-pyrazole (L) ligands, one O atom from a formate ligand and a chloride anion in an axial position [Cu—Cl = 2.4275 (7) Å] in a distorted tetra­gonal–pyramidal geometry. The Cu(II) atom in B is coordinated by two N atoms from two L ligands and two chloride anions [Cu—Cl = 2.2524 (6) Å] in a distorted square-planar geometry. In the crystal, inter­molecular N—H⋯O hydrogen bonds link mol­ecules A into centrosymmetric dimers. Inter­molecular N—H⋯Cl hydrogen bonds further link these dimers with the B mol­ecules, forming chains propagating in [101].
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spelling pubmed-31203832011-07-13 Chloridotris(3,5-dimethyl-1H-pyrazole-κN (2))(formato-κO)copper(II)–dichlorido­bis(3,5-dimethyl-1H-pyrazole-κN (2))copper(II) (2/1) Davydenko, Yuliya M. Fritsky, Igor O. Pavlenko, Vadim O. Meyer, Franc Dechert, Sebastian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Cu(CHO(2))Cl(C(5)H(8)N(2))(3)](2)·[CuCl(2)(C(5)H(8)N(2))(2)] or 2[A]·[B], contains one A mol­ecule and one half-molecule of B, located on a centre of inversion. The Cu(II) environments in A and B are different. In A, the Cu(II) atom is coordinated by three N atoms from three 3,5-dimethyl-1H-pyrazole (L) ligands, one O atom from a formate ligand and a chloride anion in an axial position [Cu—Cl = 2.4275 (7) Å] in a distorted tetra­gonal–pyramidal geometry. The Cu(II) atom in B is coordinated by two N atoms from two L ligands and two chloride anions [Cu—Cl = 2.2524 (6) Å] in a distorted square-planar geometry. In the crystal, inter­molecular N—H⋯O hydrogen bonds link mol­ecules A into centrosymmetric dimers. Inter­molecular N—H⋯Cl hydrogen bonds further link these dimers with the B mol­ecules, forming chains propagating in [101]. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120383/ /pubmed/21754628 http://dx.doi.org/10.1107/S1600536811016461 Text en © Davydenko et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Davydenko, Yuliya M.
Fritsky, Igor O.
Pavlenko, Vadim O.
Meyer, Franc
Dechert, Sebastian
Chloridotris(3,5-dimethyl-1H-pyrazole-κN (2))(formato-κO)copper(II)–dichlorido­bis(3,5-dimethyl-1H-pyrazole-κN (2))copper(II) (2/1)
title Chloridotris(3,5-dimethyl-1H-pyrazole-κN (2))(formato-κO)copper(II)–dichlorido­bis(3,5-dimethyl-1H-pyrazole-κN (2))copper(II) (2/1)
title_full Chloridotris(3,5-dimethyl-1H-pyrazole-κN (2))(formato-κO)copper(II)–dichlorido­bis(3,5-dimethyl-1H-pyrazole-κN (2))copper(II) (2/1)
title_fullStr Chloridotris(3,5-dimethyl-1H-pyrazole-κN (2))(formato-κO)copper(II)–dichlorido­bis(3,5-dimethyl-1H-pyrazole-κN (2))copper(II) (2/1)
title_full_unstemmed Chloridotris(3,5-dimethyl-1H-pyrazole-κN (2))(formato-κO)copper(II)–dichlorido­bis(3,5-dimethyl-1H-pyrazole-κN (2))copper(II) (2/1)
title_short Chloridotris(3,5-dimethyl-1H-pyrazole-κN (2))(formato-κO)copper(II)–dichlorido­bis(3,5-dimethyl-1H-pyrazole-κN (2))copper(II) (2/1)
title_sort chloridotris(3,5-dimethyl-1h-pyrazole-κn (2))(formato-κo)copper(ii)–dichlorido­bis(3,5-dimethyl-1h-pyrazole-κn (2))copper(ii) (2/1)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120383/
https://www.ncbi.nlm.nih.gov/pubmed/21754628
http://dx.doi.org/10.1107/S1600536811016461
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