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Poly[μ-aqua-aqua{μ-6-ethoxy-2-[(2-isonicotinoylhydrazinylidene)methyl]phenolato-κ(3) O,N,O′}dioxidosodiumvanadate(V)]
The V(V) atom in the polymeric title compound, [NaV(C(15)H(13)N(3)O(3))O(2)(H(2)O)(2)](n), is O,N,O′-chelated by the Schiff base dianion and is five-coordinated in a trigonal–bipramidal coordination geometry. The oxide O atoms occupy the equatorial sites and one oxide O atom is connected to the Na(I...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120385/ https://www.ncbi.nlm.nih.gov/pubmed/21754676 http://dx.doi.org/10.1107/S1600536811019106 |
Sumario: | The V(V) atom in the polymeric title compound, [NaV(C(15)H(13)N(3)O(3))O(2)(H(2)O)(2)](n), is O,N,O′-chelated by the Schiff base dianion and is five-coordinated in a trigonal–bipramidal coordination geometry. The oxide O atoms occupy the equatorial sites and one oxide O atom is connected to the Na(I) atom. The ligand simultaneously O,O′-chelates to the water-coordinated Na(I) atom; its coordination number is seven owing to an Na⋯N(pyridyl) bond. The two independent formula units, which are disposed about a false center of inversion, are connected into a layer. Adjacent layers are consolidated into a three-dimensional network by O—H⋯O and O—H⋯N hydrogen bonds. |
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