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Poly[μ-aqua-aqua­{μ-6-eth­oxy-2-[(2-isonicotinoylhydrazinyl­idene)meth­yl]phenolato-κ(3) O,N,O′}dioxidosodium­vanadate(V)]

The V(V) atom in the polymeric title compound, [NaV(C(15)H(13)N(3)O(3))O(2)(H(2)O)(2)](n), is O,N,O′-chelated by the Schiff base dianion and is five-coordinated in a trigonal–bipramidal coordination geometry. The oxide O atoms occupy the equatorial sites and one oxide O atom is connected to the Na(I...

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Detalles Bibliográficos
Autores principales: Wong, Hon Wee, Lo, Kong Mun, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120385/
https://www.ncbi.nlm.nih.gov/pubmed/21754676
http://dx.doi.org/10.1107/S1600536811019106
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author Wong, Hon Wee
Lo, Kong Mun
Ng, Seik Weng
author_facet Wong, Hon Wee
Lo, Kong Mun
Ng, Seik Weng
author_sort Wong, Hon Wee
collection PubMed
description The V(V) atom in the polymeric title compound, [NaV(C(15)H(13)N(3)O(3))O(2)(H(2)O)(2)](n), is O,N,O′-chelated by the Schiff base dianion and is five-coordinated in a trigonal–bipramidal coordination geometry. The oxide O atoms occupy the equatorial sites and one oxide O atom is connected to the Na(I) atom. The ligand simultaneously O,O′-chelates to the water-coordinated Na(I) atom; its coordination number is seven owing to an Na⋯N(pyrid­yl) bond. The two independent formula units, which are disposed about a false center of inversion, are connected into a layer. Adjacent layers are consolidated into a three-dimensional network by O—H⋯O and O—H⋯N hydrogen bonds.
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spelling pubmed-31203852011-07-13 Poly[μ-aqua-aqua­{μ-6-eth­oxy-2-[(2-isonicotinoylhydrazinyl­idene)meth­yl]phenolato-κ(3) O,N,O′}dioxidosodium­vanadate(V)] Wong, Hon Wee Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The V(V) atom in the polymeric title compound, [NaV(C(15)H(13)N(3)O(3))O(2)(H(2)O)(2)](n), is O,N,O′-chelated by the Schiff base dianion and is five-coordinated in a trigonal–bipramidal coordination geometry. The oxide O atoms occupy the equatorial sites and one oxide O atom is connected to the Na(I) atom. The ligand simultaneously O,O′-chelates to the water-coordinated Na(I) atom; its coordination number is seven owing to an Na⋯N(pyrid­yl) bond. The two independent formula units, which are disposed about a false center of inversion, are connected into a layer. Adjacent layers are consolidated into a three-dimensional network by O—H⋯O and O—H⋯N hydrogen bonds. International Union of Crystallography 2011-05-25 /pmc/articles/PMC3120385/ /pubmed/21754676 http://dx.doi.org/10.1107/S1600536811019106 Text en © Wong et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wong, Hon Wee
Lo, Kong Mun
Ng, Seik Weng
Poly[μ-aqua-aqua­{μ-6-eth­oxy-2-[(2-isonicotinoylhydrazinyl­idene)meth­yl]phenolato-κ(3) O,N,O′}dioxidosodium­vanadate(V)]
title Poly[μ-aqua-aqua­{μ-6-eth­oxy-2-[(2-isonicotinoylhydrazinyl­idene)meth­yl]phenolato-κ(3) O,N,O′}dioxidosodium­vanadate(V)]
title_full Poly[μ-aqua-aqua­{μ-6-eth­oxy-2-[(2-isonicotinoylhydrazinyl­idene)meth­yl]phenolato-κ(3) O,N,O′}dioxidosodium­vanadate(V)]
title_fullStr Poly[μ-aqua-aqua­{μ-6-eth­oxy-2-[(2-isonicotinoylhydrazinyl­idene)meth­yl]phenolato-κ(3) O,N,O′}dioxidosodium­vanadate(V)]
title_full_unstemmed Poly[μ-aqua-aqua­{μ-6-eth­oxy-2-[(2-isonicotinoylhydrazinyl­idene)meth­yl]phenolato-κ(3) O,N,O′}dioxidosodium­vanadate(V)]
title_short Poly[μ-aqua-aqua­{μ-6-eth­oxy-2-[(2-isonicotinoylhydrazinyl­idene)meth­yl]phenolato-κ(3) O,N,O′}dioxidosodium­vanadate(V)]
title_sort poly[μ-aqua-aqua­{μ-6-eth­oxy-2-[(2-isonicotinoylhydrazinyl­idene)meth­yl]phenolato-κ(3) o,n,o′}dioxidosodium­vanadate(v)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120385/
https://www.ncbi.nlm.nih.gov/pubmed/21754676
http://dx.doi.org/10.1107/S1600536811019106
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