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Poly[μ-aqua-aqua{μ-6-ethoxy-2-[(2-isonicotinoylhydrazinylidene)methyl]phenolato-κ(3) O,N,O′}dioxidosodiumvanadate(V)]
The V(V) atom in the polymeric title compound, [NaV(C(15)H(13)N(3)O(3))O(2)(H(2)O)(2)](n), is O,N,O′-chelated by the Schiff base dianion and is five-coordinated in a trigonal–bipramidal coordination geometry. The oxide O atoms occupy the equatorial sites and one oxide O atom is connected to the Na(I...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120385/ https://www.ncbi.nlm.nih.gov/pubmed/21754676 http://dx.doi.org/10.1107/S1600536811019106 |
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author | Wong, Hon Wee Lo, Kong Mun Ng, Seik Weng |
author_facet | Wong, Hon Wee Lo, Kong Mun Ng, Seik Weng |
author_sort | Wong, Hon Wee |
collection | PubMed |
description | The V(V) atom in the polymeric title compound, [NaV(C(15)H(13)N(3)O(3))O(2)(H(2)O)(2)](n), is O,N,O′-chelated by the Schiff base dianion and is five-coordinated in a trigonal–bipramidal coordination geometry. The oxide O atoms occupy the equatorial sites and one oxide O atom is connected to the Na(I) atom. The ligand simultaneously O,O′-chelates to the water-coordinated Na(I) atom; its coordination number is seven owing to an Na⋯N(pyridyl) bond. The two independent formula units, which are disposed about a false center of inversion, are connected into a layer. Adjacent layers are consolidated into a three-dimensional network by O—H⋯O and O—H⋯N hydrogen bonds. |
format | Online Article Text |
id | pubmed-3120385 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31203852011-07-13 Poly[μ-aqua-aqua{μ-6-ethoxy-2-[(2-isonicotinoylhydrazinylidene)methyl]phenolato-κ(3) O,N,O′}dioxidosodiumvanadate(V)] Wong, Hon Wee Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The V(V) atom in the polymeric title compound, [NaV(C(15)H(13)N(3)O(3))O(2)(H(2)O)(2)](n), is O,N,O′-chelated by the Schiff base dianion and is five-coordinated in a trigonal–bipramidal coordination geometry. The oxide O atoms occupy the equatorial sites and one oxide O atom is connected to the Na(I) atom. The ligand simultaneously O,O′-chelates to the water-coordinated Na(I) atom; its coordination number is seven owing to an Na⋯N(pyridyl) bond. The two independent formula units, which are disposed about a false center of inversion, are connected into a layer. Adjacent layers are consolidated into a three-dimensional network by O—H⋯O and O—H⋯N hydrogen bonds. International Union of Crystallography 2011-05-25 /pmc/articles/PMC3120385/ /pubmed/21754676 http://dx.doi.org/10.1107/S1600536811019106 Text en © Wong et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wong, Hon Wee Lo, Kong Mun Ng, Seik Weng Poly[μ-aqua-aqua{μ-6-ethoxy-2-[(2-isonicotinoylhydrazinylidene)methyl]phenolato-κ(3) O,N,O′}dioxidosodiumvanadate(V)] |
title | Poly[μ-aqua-aqua{μ-6-ethoxy-2-[(2-isonicotinoylhydrazinylidene)methyl]phenolato-κ(3)
O,N,O′}dioxidosodiumvanadate(V)] |
title_full | Poly[μ-aqua-aqua{μ-6-ethoxy-2-[(2-isonicotinoylhydrazinylidene)methyl]phenolato-κ(3)
O,N,O′}dioxidosodiumvanadate(V)] |
title_fullStr | Poly[μ-aqua-aqua{μ-6-ethoxy-2-[(2-isonicotinoylhydrazinylidene)methyl]phenolato-κ(3)
O,N,O′}dioxidosodiumvanadate(V)] |
title_full_unstemmed | Poly[μ-aqua-aqua{μ-6-ethoxy-2-[(2-isonicotinoylhydrazinylidene)methyl]phenolato-κ(3)
O,N,O′}dioxidosodiumvanadate(V)] |
title_short | Poly[μ-aqua-aqua{μ-6-ethoxy-2-[(2-isonicotinoylhydrazinylidene)methyl]phenolato-κ(3)
O,N,O′}dioxidosodiumvanadate(V)] |
title_sort | poly[μ-aqua-aqua{μ-6-ethoxy-2-[(2-isonicotinoylhydrazinylidene)methyl]phenolato-κ(3)
o,n,o′}dioxidosodiumvanadate(v)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120385/ https://www.ncbi.nlm.nih.gov/pubmed/21754676 http://dx.doi.org/10.1107/S1600536811019106 |
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