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(E,E)-1,2-Bis(2,4,5-trimethoxybenzylidene)hydrazine
The asymmetric unit of the title compound, C(20)H(24)N(2)O(6), contains one half-molecule, the complete molecule being generated by a crystallographic inversion centre. The molecule is nearly planar with a dihedral angle between the two benzene rings of 0.03 (4)° and the central C/N/N/C plane mak...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120387/ https://www.ncbi.nlm.nih.gov/pubmed/21754887 http://dx.doi.org/10.1107/S1600536811019040 |
Sumario: | The asymmetric unit of the title compound, C(20)H(24)N(2)O(6), contains one half-molecule, the complete molecule being generated by a crystallographic inversion centre. The molecule is nearly planar with a dihedral angle between the two benzene rings of 0.03 (4)° and the central C/N/N/C plane making a dihedral angle of 8.59 (7)° with each of its two adjacent benzene rings. The two methoxy groups at the ortho and meta positions are slightly twisted [C—O—C—C torsion angles = 7.23 (12) and 5.73 (13)°], whereas the methoxy group at the para position is almost coplanar with the attached benzene ring [C—O—C—C torsion angle = −2.02 (13)°]. The crystal structure is stabilized by a weak C—H⋯π interaction. |
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