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Bis(3-methylpyridinium) tetra(chlorido/bromido)cuprate(II)
The structure of the title salt, (C(6)H(8)N)(2)[CuCl(3.4)Br(0.6)], consists of two 3-methylpyridinium cations and a distorted tetrahedral [CuCl(3.4)Br(0.6)](2−) dianion. Substitutional disorder with Br is exhibited for three of the Cl atoms of the anion, giving a mixed chloride/bromide cuprate(II)...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120388/ https://www.ncbi.nlm.nih.gov/pubmed/21754672 http://dx.doi.org/10.1107/S1600536811019076 |
| _version_ | 1782206667879874560 |
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| author | Kim, Young-Inn Lim, Hyun-Soo Kang, Sung Kwon |
| author_facet | Kim, Young-Inn Lim, Hyun-Soo Kang, Sung Kwon |
| author_sort | Kim, Young-Inn |
| collection | PubMed |
| description | The structure of the title salt, (C(6)H(8)N)(2)[CuCl(3.4)Br(0.6)], consists of two 3-methylpyridinium cations and a distorted tetrahedral [CuCl(3.4)Br(0.6)](2−) dianion. Substitutional disorder with Br is exhibited for three of the Cl atoms of the anion, giving a mixed chloride/bromide cuprate(II) anion. In the crystal, intermolecular N—H⋯Cl hydrogen bonds link two cations to one anion, forming a three-ion aggregate. These are connected into a supramolecular chain along the b axis via π–π interactions between the pyridinium rings [centroid–centroid distance = 3.743 (3) Å]. |
| format | Online Article Text |
| id | pubmed-3120388 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-31203882011-07-13 Bis(3-methylpyridinium) tetra(chlorido/bromido)cuprate(II) Kim, Young-Inn Lim, Hyun-Soo Kang, Sung Kwon Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title salt, (C(6)H(8)N)(2)[CuCl(3.4)Br(0.6)], consists of two 3-methylpyridinium cations and a distorted tetrahedral [CuCl(3.4)Br(0.6)](2−) dianion. Substitutional disorder with Br is exhibited for three of the Cl atoms of the anion, giving a mixed chloride/bromide cuprate(II) anion. In the crystal, intermolecular N—H⋯Cl hydrogen bonds link two cations to one anion, forming a three-ion aggregate. These are connected into a supramolecular chain along the b axis via π–π interactions between the pyridinium rings [centroid–centroid distance = 3.743 (3) Å]. International Union of Crystallography 2011-05-25 /pmc/articles/PMC3120388/ /pubmed/21754672 http://dx.doi.org/10.1107/S1600536811019076 Text en © Kim et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Kim, Young-Inn Lim, Hyun-Soo Kang, Sung Kwon Bis(3-methylpyridinium) tetra(chlorido/bromido)cuprate(II) |
| title | Bis(3-methylpyridinium) tetra(chlorido/bromido)cuprate(II) |
| title_full | Bis(3-methylpyridinium) tetra(chlorido/bromido)cuprate(II) |
| title_fullStr | Bis(3-methylpyridinium) tetra(chlorido/bromido)cuprate(II) |
| title_full_unstemmed | Bis(3-methylpyridinium) tetra(chlorido/bromido)cuprate(II) |
| title_short | Bis(3-methylpyridinium) tetra(chlorido/bromido)cuprate(II) |
| title_sort | bis(3-methylpyridinium) tetra(chlorido/bromido)cuprate(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120388/ https://www.ncbi.nlm.nih.gov/pubmed/21754672 http://dx.doi.org/10.1107/S1600536811019076 |
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