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Dichlorido(3-phenylindenylidene)bis(triphenylphosphane)ruthenium(II) tetrahydrofuran disolvate
The Ru(II) atom in the title compound, [RuCl(2)(C(15)H(10))(C(18)H(15)P)(2)]·2C(4)H(8)O, has a distorted square-pyramidal conformation. The P and Cl atoms are at the base of the pyramid and the Ru—C(indenylidene) bond is in the axial position. The two Cl ligands and the two phosphane ligands are in...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120390/ https://www.ncbi.nlm.nih.gov/pubmed/21754621 http://dx.doi.org/10.1107/S1600536811016692 |
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author | Bats, Jan W. Pérez Gomes, Jessica Doppiu, Angelino Hashmi, A. Stephen K. |
author_facet | Bats, Jan W. Pérez Gomes, Jessica Doppiu, Angelino Hashmi, A. Stephen K. |
author_sort | Bats, Jan W. |
collection | PubMed |
description | The Ru(II) atom in the title compound, [RuCl(2)(C(15)H(10))(C(18)H(15)P)(2)]·2C(4)H(8)O, has a distorted square-pyramidal conformation. The P and Cl atoms are at the base of the pyramid and the Ru—C(indenylidene) bond is in the axial position. The two Cl ligands and the two phosphane ligands are in trans positions. The Cl—Ru—Cl and P—Ru—P angles are 157.71 (2) and 166.83 (2)°, respectively. The two independent tetrahydrofuran (THF) solvent molecules are disordered. One THF molecule was refined using a split-atom model. The second THF molecule was accounted for by using program PLATON/SQUEEZE [Spek (2009 ▶). Acta Cryst. D65, 148–155]. The molecular conformation shows three intramolecular C—H⋯Cl contacts and two C—H⋯π interactions while the crystal packing features an intermolecular C—H⋯Cl contact and two very weak intermolecular C—H⋯π contacts. |
format | Online Article Text |
id | pubmed-3120390 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31203902011-07-13 Dichlorido(3-phenylindenylidene)bis(triphenylphosphane)ruthenium(II) tetrahydrofuran disolvate Bats, Jan W. Pérez Gomes, Jessica Doppiu, Angelino Hashmi, A. Stephen K. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Ru(II) atom in the title compound, [RuCl(2)(C(15)H(10))(C(18)H(15)P)(2)]·2C(4)H(8)O, has a distorted square-pyramidal conformation. The P and Cl atoms are at the base of the pyramid and the Ru—C(indenylidene) bond is in the axial position. The two Cl ligands and the two phosphane ligands are in trans positions. The Cl—Ru—Cl and P—Ru—P angles are 157.71 (2) and 166.83 (2)°, respectively. The two independent tetrahydrofuran (THF) solvent molecules are disordered. One THF molecule was refined using a split-atom model. The second THF molecule was accounted for by using program PLATON/SQUEEZE [Spek (2009 ▶). Acta Cryst. D65, 148–155]. The molecular conformation shows three intramolecular C—H⋯Cl contacts and two C—H⋯π interactions while the crystal packing features an intermolecular C—H⋯Cl contact and two very weak intermolecular C—H⋯π contacts. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120390/ /pubmed/21754621 http://dx.doi.org/10.1107/S1600536811016692 Text en © Bats et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Bats, Jan W. Pérez Gomes, Jessica Doppiu, Angelino Hashmi, A. Stephen K. Dichlorido(3-phenylindenylidene)bis(triphenylphosphane)ruthenium(II) tetrahydrofuran disolvate |
title | Dichlorido(3-phenylindenylidene)bis(triphenylphosphane)ruthenium(II) tetrahydrofuran disolvate |
title_full | Dichlorido(3-phenylindenylidene)bis(triphenylphosphane)ruthenium(II) tetrahydrofuran disolvate |
title_fullStr | Dichlorido(3-phenylindenylidene)bis(triphenylphosphane)ruthenium(II) tetrahydrofuran disolvate |
title_full_unstemmed | Dichlorido(3-phenylindenylidene)bis(triphenylphosphane)ruthenium(II) tetrahydrofuran disolvate |
title_short | Dichlorido(3-phenylindenylidene)bis(triphenylphosphane)ruthenium(II) tetrahydrofuran disolvate |
title_sort | dichlorido(3-phenylindenylidene)bis(triphenylphosphane)ruthenium(ii) tetrahydrofuran disolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120390/ https://www.ncbi.nlm.nih.gov/pubmed/21754621 http://dx.doi.org/10.1107/S1600536811016692 |
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