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Dichlorido(3-phenyl­indenyl­idene)bis­(triphenyl­phosphane)ruthenium(II) tetra­hydro­furan disolvate

The Ru(II) atom in the title compound, [RuCl(2)(C(15)H(10))(C(18)H(15)P)(2)]·2C(4)H(8)O, has a distorted square-pyramidal conformation. The P and Cl atoms are at the base of the pyramid and the Ru—C(indenyl­idene) bond is in the axial position. The two Cl ligands and the two phosphane ligands are in...

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Autores principales: Bats, Jan W., Pérez Gomes, Jessica, Doppiu, Angelino, Hashmi, A. Stephen K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120390/
https://www.ncbi.nlm.nih.gov/pubmed/21754621
http://dx.doi.org/10.1107/S1600536811016692
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author Bats, Jan W.
Pérez Gomes, Jessica
Doppiu, Angelino
Hashmi, A. Stephen K.
author_facet Bats, Jan W.
Pérez Gomes, Jessica
Doppiu, Angelino
Hashmi, A. Stephen K.
author_sort Bats, Jan W.
collection PubMed
description The Ru(II) atom in the title compound, [RuCl(2)(C(15)H(10))(C(18)H(15)P)(2)]·2C(4)H(8)O, has a distorted square-pyramidal conformation. The P and Cl atoms are at the base of the pyramid and the Ru—C(indenyl­idene) bond is in the axial position. The two Cl ligands and the two phosphane ligands are in trans positions. The Cl—Ru—Cl and P—Ru—P angles are 157.71 (2) and 166.83 (2)°, respectively. The two independent tetra­hydro­furan (THF) solvent mol­ecules are disordered. One THF mol­ecule was refined using a split-atom model. The second THF mol­ecule was accounted for by using program PLATON/SQUEEZE [Spek (2009 ▶). Acta Cryst. D65, 148–155]. The molecular conformation shows three intramolecular C—H⋯Cl contacts and two C—H⋯π interactions while the crystal packing features an intermolecular C—H⋯Cl contact and two very weak intermolecular C—H⋯π contacts.
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spelling pubmed-31203902011-07-13 Dichlorido(3-phenyl­indenyl­idene)bis­(triphenyl­phosphane)ruthenium(II) tetra­hydro­furan disolvate Bats, Jan W. Pérez Gomes, Jessica Doppiu, Angelino Hashmi, A. Stephen K. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Ru(II) atom in the title compound, [RuCl(2)(C(15)H(10))(C(18)H(15)P)(2)]·2C(4)H(8)O, has a distorted square-pyramidal conformation. The P and Cl atoms are at the base of the pyramid and the Ru—C(indenyl­idene) bond is in the axial position. The two Cl ligands and the two phosphane ligands are in trans positions. The Cl—Ru—Cl and P—Ru—P angles are 157.71 (2) and 166.83 (2)°, respectively. The two independent tetra­hydro­furan (THF) solvent mol­ecules are disordered. One THF mol­ecule was refined using a split-atom model. The second THF mol­ecule was accounted for by using program PLATON/SQUEEZE [Spek (2009 ▶). Acta Cryst. D65, 148–155]. The molecular conformation shows three intramolecular C—H⋯Cl contacts and two C—H⋯π interactions while the crystal packing features an intermolecular C—H⋯Cl contact and two very weak intermolecular C—H⋯π contacts. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120390/ /pubmed/21754621 http://dx.doi.org/10.1107/S1600536811016692 Text en © Bats et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bats, Jan W.
Pérez Gomes, Jessica
Doppiu, Angelino
Hashmi, A. Stephen K.
Dichlorido(3-phenyl­indenyl­idene)bis­(triphenyl­phosphane)ruthenium(II) tetra­hydro­furan disolvate
title Dichlorido(3-phenyl­indenyl­idene)bis­(triphenyl­phosphane)ruthenium(II) tetra­hydro­furan disolvate
title_full Dichlorido(3-phenyl­indenyl­idene)bis­(triphenyl­phosphane)ruthenium(II) tetra­hydro­furan disolvate
title_fullStr Dichlorido(3-phenyl­indenyl­idene)bis­(triphenyl­phosphane)ruthenium(II) tetra­hydro­furan disolvate
title_full_unstemmed Dichlorido(3-phenyl­indenyl­idene)bis­(triphenyl­phosphane)ruthenium(II) tetra­hydro­furan disolvate
title_short Dichlorido(3-phenyl­indenyl­idene)bis­(triphenyl­phosphane)ruthenium(II) tetra­hydro­furan disolvate
title_sort dichlorido(3-phenyl­indenyl­idene)bis­(triphenyl­phosphane)ruthenium(ii) tetra­hydro­furan disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120390/
https://www.ncbi.nlm.nih.gov/pubmed/21754621
http://dx.doi.org/10.1107/S1600536811016692
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