Bis(2-hy­droxy­benzoato-κO)bis­[3-(4-meth­oxy­phen­yl)-4-(4-methyl­phen­yl)-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]copper(II) dihydrate

In the title complex, [Cu(C(7)H(5)O(3))(2)(C(21)H(18)N(4)O)(2)]·2H(2)O, the Cu(II) atom is located on a centre of inversion and exists in a tetra­gonally distorted octahedral geometry with a CuN(4)O(2) chromophore. The intra­molecular O—H⋯O hydrogen bond is highly strained due to the mol­ecular geom...

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Detalles Bibliográficos
Autores principales: Liu, Yan, Wang, Zuoxiang, Zhang, Hai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120391/
https://www.ncbi.nlm.nih.gov/pubmed/21754601
http://dx.doi.org/10.1107/S1600536811016126
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author Liu, Yan
Wang, Zuoxiang
Zhang, Hai
author_facet Liu, Yan
Wang, Zuoxiang
Zhang, Hai
author_sort Liu, Yan
collection PubMed
description In the title complex, [Cu(C(7)H(5)O(3))(2)(C(21)H(18)N(4)O)(2)]·2H(2)O, the Cu(II) atom is located on a centre of inversion and exists in a tetra­gonally distorted octahedral geometry with a CuN(4)O(2) chromophore. The intra­molecular O—H⋯O hydrogen bond is highly strained due to the mol­ecular geometry and, as a result, is much shorter than expected. Inter­molecular C—H⋯O and C—H⋯O inter­actions are also observed.
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spelling pubmed-31203912011-07-13 Bis(2-hy­droxy­benzoato-κO)bis­[3-(4-meth­oxy­phen­yl)-4-(4-methyl­phen­yl)-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]copper(II) dihydrate Liu, Yan Wang, Zuoxiang Zhang, Hai Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(7)H(5)O(3))(2)(C(21)H(18)N(4)O)(2)]·2H(2)O, the Cu(II) atom is located on a centre of inversion and exists in a tetra­gonally distorted octahedral geometry with a CuN(4)O(2) chromophore. The intra­molecular O—H⋯O hydrogen bond is highly strained due to the mol­ecular geometry and, as a result, is much shorter than expected. Inter­molecular C—H⋯O and C—H⋯O inter­actions are also observed. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120391/ /pubmed/21754601 http://dx.doi.org/10.1107/S1600536811016126 Text en © Liu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Yan
Wang, Zuoxiang
Zhang, Hai
Bis(2-hy­droxy­benzoato-κO)bis­[3-(4-meth­oxy­phen­yl)-4-(4-methyl­phen­yl)-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]copper(II) dihydrate
title Bis(2-hy­droxy­benzoato-κO)bis­[3-(4-meth­oxy­phen­yl)-4-(4-methyl­phen­yl)-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]copper(II) dihydrate
title_full Bis(2-hy­droxy­benzoato-κO)bis­[3-(4-meth­oxy­phen­yl)-4-(4-methyl­phen­yl)-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]copper(II) dihydrate
title_fullStr Bis(2-hy­droxy­benzoato-κO)bis­[3-(4-meth­oxy­phen­yl)-4-(4-methyl­phen­yl)-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]copper(II) dihydrate
title_full_unstemmed Bis(2-hy­droxy­benzoato-κO)bis­[3-(4-meth­oxy­phen­yl)-4-(4-methyl­phen­yl)-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]copper(II) dihydrate
title_short Bis(2-hy­droxy­benzoato-κO)bis­[3-(4-meth­oxy­phen­yl)-4-(4-methyl­phen­yl)-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]copper(II) dihydrate
title_sort bis(2-hy­droxy­benzoato-κo)bis­[3-(4-meth­oxy­phen­yl)-4-(4-methyl­phen­yl)-5-(2-pyrid­yl)-4h-1,2,4-triazole-κ(2) n (1),n (5)]copper(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120391/
https://www.ncbi.nlm.nih.gov/pubmed/21754601
http://dx.doi.org/10.1107/S1600536811016126
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AT zhanghai bis2hydroxybenzoatokobis34methoxyphenyl44methylphenyl52pyridyl4h124triazolek2n1n5copperiidihydrate

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