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Tetra­chloridobis(dibenzyl sulfoxide-κO)tin(IV)

The six-coordinate Sn(IV) atom in the title compound, [SnCl(4)(C(14)H(14)OS)(2)], exists in a cis-SnCl(4)O(2) octa­hedral geometry. Of the four Cl atoms, two are close to adjacent S atoms [Cl⋯S = 3.320 (1) and 3.376 (1) Å]; the Sn—Cl bonds involving these two Cl atoms are longer than the other two S...

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Detalles Bibliográficos
Autores principales: Keng, Thy Chun, Lo, Kong Mun, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120392/
https://www.ncbi.nlm.nih.gov/pubmed/21754572
http://dx.doi.org/10.1107/S1600536811015704
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author Keng, Thy Chun
Lo, Kong Mun
Ng, Seik Weng
author_facet Keng, Thy Chun
Lo, Kong Mun
Ng, Seik Weng
author_sort Keng, Thy Chun
collection PubMed
description The six-coordinate Sn(IV) atom in the title compound, [SnCl(4)(C(14)H(14)OS)(2)], exists in a cis-SnCl(4)O(2) octa­hedral geometry. Of the four Cl atoms, two are close to adjacent S atoms [Cl⋯S = 3.320 (1) and 3.376 (1) Å]; the Sn—Cl bonds involving these two Cl atoms are longer than the other two Sn—Cl bonds.
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spelling pubmed-31203922011-07-13 Tetra­chloridobis(dibenzyl sulfoxide-κO)tin(IV) Keng, Thy Chun Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The six-coordinate Sn(IV) atom in the title compound, [SnCl(4)(C(14)H(14)OS)(2)], exists in a cis-SnCl(4)O(2) octa­hedral geometry. Of the four Cl atoms, two are close to adjacent S atoms [Cl⋯S = 3.320 (1) and 3.376 (1) Å]; the Sn—Cl bonds involving these two Cl atoms are longer than the other two Sn—Cl bonds. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120392/ /pubmed/21754572 http://dx.doi.org/10.1107/S1600536811015704 Text en © Keng et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Keng, Thy Chun
Lo, Kong Mun
Ng, Seik Weng
Tetra­chloridobis(dibenzyl sulfoxide-κO)tin(IV)
title Tetra­chloridobis(dibenzyl sulfoxide-κO)tin(IV)
title_full Tetra­chloridobis(dibenzyl sulfoxide-κO)tin(IV)
title_fullStr Tetra­chloridobis(dibenzyl sulfoxide-κO)tin(IV)
title_full_unstemmed Tetra­chloridobis(dibenzyl sulfoxide-κO)tin(IV)
title_short Tetra­chloridobis(dibenzyl sulfoxide-κO)tin(IV)
title_sort tetra­chloridobis(dibenzyl sulfoxide-κo)tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120392/
https://www.ncbi.nlm.nih.gov/pubmed/21754572
http://dx.doi.org/10.1107/S1600536811015704
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AT lokongmun tetrachloridobisdibenzylsulfoxidekotiniv
AT ngseikweng tetrachloridobisdibenzylsulfoxidekotiniv