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Bis(1,10-phenanthroline-κ(2) N,N′)bis(thiocyanato-κN)cadmium
The title compound, [Cd(NCS)(2)(C(12)H(8)N(2))(2)], has been obtained from the decomposition reaction of dithiooxamide in a dimethylformamide solution containing 1,10-phenanthroline (phen) and Cd(NO(3))(2)·4H(2)O. Its crystal structure is formed by monuclear Cd(II) entities in which the metal atom...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120395/ https://www.ncbi.nlm.nih.gov/pubmed/21754607 http://dx.doi.org/10.1107/S160053681101289X |
| Sumario: | The title compound, [Cd(NCS)(2)(C(12)H(8)N(2))(2)], has been obtained from the decomposition reaction of dithiooxamide in a dimethylformamide solution containing 1,10-phenanthroline (phen) and Cd(NO(3))(2)·4H(2)O. Its crystal structure is formed by monuclear Cd(II) entities in which the metal atom is sited on a twofold rotation axis. The Cd(II) atom is six-coordinated in the form of a distorted octahedron by two chelating phenanthroline molecules and two thiocyanate anions coordinated through their N atoms. In the crystal, C—H⋯N hydrogen bonds are established between the phenanthroline and thiocyanate ligands of neighbouring complexes. |
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