Bis(1,10-phenanthroline-κ(2) N,N′)bis­(thio­cyanato-κN)cadmium

The title compound, [Cd(NCS)(2)(C(12)H(8)N(2))(2)], has been obtained from the decomposition reaction of dithio­oxamide in a dimethyl­formamide solution containing 1,10-phenanthroline (phen) and Cd(NO(3))(2)·4H(2)O. Its crystal structure is formed by monuclear Cd(II) entities in which the metal atom...

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Detalles Bibliográficos
Autores principales: Vallejo, Daniel, Beobide, Garikoitz, Castillo, Oscar, Luque, Antonio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120395/
https://www.ncbi.nlm.nih.gov/pubmed/21754607
http://dx.doi.org/10.1107/S160053681101289X
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author Vallejo, Daniel
Beobide, Garikoitz
Castillo, Oscar
Luque, Antonio
author_facet Vallejo, Daniel
Beobide, Garikoitz
Castillo, Oscar
Luque, Antonio
author_sort Vallejo, Daniel
collection PubMed
description The title compound, [Cd(NCS)(2)(C(12)H(8)N(2))(2)], has been obtained from the decomposition reaction of dithio­oxamide in a dimethyl­formamide solution containing 1,10-phenanthroline (phen) and Cd(NO(3))(2)·4H(2)O. Its crystal structure is formed by monuclear Cd(II) entities in which the metal atom is sited on a twofold rotation axis. The Cd(II) atom is six-coordinated in the form of a distorted octa­hedron by two chelating phenanthroline mol­ecules and two thio­cyanate anions coordinated through their N atoms. In the crystal, C—H⋯N hydrogen bonds are established between the phenanthroline and thio­cyanate ligands of neighbouring complexes.
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spelling pubmed-31203952011-07-13 Bis(1,10-phenanthroline-κ(2) N,N′)bis­(thio­cyanato-κN)cadmium Vallejo, Daniel Beobide, Garikoitz Castillo, Oscar Luque, Antonio Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cd(NCS)(2)(C(12)H(8)N(2))(2)], has been obtained from the decomposition reaction of dithio­oxamide in a dimethyl­formamide solution containing 1,10-phenanthroline (phen) and Cd(NO(3))(2)·4H(2)O. Its crystal structure is formed by monuclear Cd(II) entities in which the metal atom is sited on a twofold rotation axis. The Cd(II) atom is six-coordinated in the form of a distorted octa­hedron by two chelating phenanthroline mol­ecules and two thio­cyanate anions coordinated through their N atoms. In the crystal, C—H⋯N hydrogen bonds are established between the phenanthroline and thio­cyanate ligands of neighbouring complexes. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120395/ /pubmed/21754607 http://dx.doi.org/10.1107/S160053681101289X Text en © Vallejo et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Vallejo, Daniel
Beobide, Garikoitz
Castillo, Oscar
Luque, Antonio
Bis(1,10-phenanthroline-κ(2) N,N′)bis­(thio­cyanato-κN)cadmium
title Bis(1,10-phenanthroline-κ(2) N,N′)bis­(thio­cyanato-κN)cadmium
title_full Bis(1,10-phenanthroline-κ(2) N,N′)bis­(thio­cyanato-κN)cadmium
title_fullStr Bis(1,10-phenanthroline-κ(2) N,N′)bis­(thio­cyanato-κN)cadmium
title_full_unstemmed Bis(1,10-phenanthroline-κ(2) N,N′)bis­(thio­cyanato-κN)cadmium
title_short Bis(1,10-phenanthroline-κ(2) N,N′)bis­(thio­cyanato-κN)cadmium
title_sort bis(1,10-phenanthroline-κ(2) n,n′)bis­(thio­cyanato-κn)cadmium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120395/
https://www.ncbi.nlm.nih.gov/pubmed/21754607
http://dx.doi.org/10.1107/S160053681101289X
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