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5-(1H-Tetrazol-5-yl)-1H-indole monohydrate
In the title compound, C(9)H(7)N(5)·H(2)O, the interplanar angles between the benzene and tetrazole rings and between the benzene and imidazole rings are 8.71 (3) and 1.32 (2)°, respectively. In the crystal, strong N—H⋯N hydrogen bonds link the organic 5-(1H-tetrazol-5-yl)-1H-indole molecules in...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120397/ https://www.ncbi.nlm.nih.gov/pubmed/21754912 http://dx.doi.org/10.1107/S1600536811018575 |
Sumario: | In the title compound, C(9)H(7)N(5)·H(2)O, the interplanar angles between the benzene and tetrazole rings and between the benzene and imidazole rings are 8.71 (3) and 1.32 (2)°, respectively. In the crystal, strong N—H⋯N hydrogen bonds link the organic 5-(1H-tetrazol-5-yl)-1H-indole molecules into chains extended along the b axis. The chains are further interconnected into layers parallel to (100) via strong O—H⋯N and N—H⋯O hydrogen bonds. Furthermore, the layers are interconnected via strong O—H⋯N hydrogen bonds. Moreover, cohesion between the layers is provided by the π–π interactions between the imidazole, tetrazole and benzene rings with centroid–centroid distances of 3.766 (2), 3.832 (2) and 3.733 (2) Å. |
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