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catena-Poly[[[bis­(3-hy­droxy­adamantane-1-carboxyl­ato-κO (1))(3-hy­droxy­adamantane-1-carb­oxy­lic acid-κO (1))zinc(II)]-μ(2)-4,4′-bipyridine] monohydrate]

In the title coordination polymer, {[Zn(C(11)H(15)O(3))(2)(C(10)H(8)N(2))(C(11)H(16)O(3))]·H(2)O}(n), the Zn(II) ion is five coordinated by two N atoms from two 4,4′-bipyridine (4,4′-bpy) mol­ecules and three O atoms from two 3-hy­droxy­adamantane-1-carboxyl­ate anions (L) and one 3-hy­droxy­adamant...

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Detalles Bibliográficos
Autores principales: Shen, Jin-Bei, Guan, Quan-Yin, Chen, Xiao-Ju, Zhao, Guo-Liang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120402/
https://www.ncbi.nlm.nih.gov/pubmed/21754615
http://dx.doi.org/10.1107/S1600536811016424
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author Shen, Jin-Bei
Guan, Quan-Yin
Chen, Xiao-Ju
Zhao, Guo-Liang
author_facet Shen, Jin-Bei
Guan, Quan-Yin
Chen, Xiao-Ju
Zhao, Guo-Liang
author_sort Shen, Jin-Bei
collection PubMed
description In the title coordination polymer, {[Zn(C(11)H(15)O(3))(2)(C(10)H(8)N(2))(C(11)H(16)O(3))]·H(2)O}(n), the Zn(II) ion is five coordinated by two N atoms from two 4,4′-bipyridine (4,4′-bpy) mol­ecules and three O atoms from two 3-hy­droxy­adamantane-1-carboxyl­ate anions (L) and one 3-hy­droxy­adamantane-1-carb­oxy­lic acid (HL) mol­ecule. The resulting coordination polyhedron is a near regular ZnN(2)O(3) trigonal bipyramid, with the N atoms in axial sites. The 4,4′-bpy mol­ecules [dihedral angle between the aromatic rings = 17.2 (2)°] act as bridges, connecting the metal ions into an infinite polymeric chain propagating in [[Image: see text]01]. O—H⋯O hydrogen bonds help to consolidate the packing.
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spelling pubmed-31204022011-07-13 catena-Poly[[[bis­(3-hy­droxy­adamantane-1-carboxyl­ato-κO (1))(3-hy­droxy­adamantane-1-carb­oxy­lic acid-κO (1))zinc(II)]-μ(2)-4,4′-bipyridine] monohydrate] Shen, Jin-Bei Guan, Quan-Yin Chen, Xiao-Ju Zhao, Guo-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, {[Zn(C(11)H(15)O(3))(2)(C(10)H(8)N(2))(C(11)H(16)O(3))]·H(2)O}(n), the Zn(II) ion is five coordinated by two N atoms from two 4,4′-bipyridine (4,4′-bpy) mol­ecules and three O atoms from two 3-hy­droxy­adamantane-1-carboxyl­ate anions (L) and one 3-hy­droxy­adamantane-1-carb­oxy­lic acid (HL) mol­ecule. The resulting coordination polyhedron is a near regular ZnN(2)O(3) trigonal bipyramid, with the N atoms in axial sites. The 4,4′-bpy mol­ecules [dihedral angle between the aromatic rings = 17.2 (2)°] act as bridges, connecting the metal ions into an infinite polymeric chain propagating in [[Image: see text]01]. O—H⋯O hydrogen bonds help to consolidate the packing. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120402/ /pubmed/21754615 http://dx.doi.org/10.1107/S1600536811016424 Text en © Shen et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shen, Jin-Bei
Guan, Quan-Yin
Chen, Xiao-Ju
Zhao, Guo-Liang
catena-Poly[[[bis­(3-hy­droxy­adamantane-1-carboxyl­ato-κO (1))(3-hy­droxy­adamantane-1-carb­oxy­lic acid-κO (1))zinc(II)]-μ(2)-4,4′-bipyridine] monohydrate]
title catena-Poly[[[bis­(3-hy­droxy­adamantane-1-carboxyl­ato-κO (1))(3-hy­droxy­adamantane-1-carb­oxy­lic acid-κO (1))zinc(II)]-μ(2)-4,4′-bipyridine] monohydrate]
title_full catena-Poly[[[bis­(3-hy­droxy­adamantane-1-carboxyl­ato-κO (1))(3-hy­droxy­adamantane-1-carb­oxy­lic acid-κO (1))zinc(II)]-μ(2)-4,4′-bipyridine] monohydrate]
title_fullStr catena-Poly[[[bis­(3-hy­droxy­adamantane-1-carboxyl­ato-κO (1))(3-hy­droxy­adamantane-1-carb­oxy­lic acid-κO (1))zinc(II)]-μ(2)-4,4′-bipyridine] monohydrate]
title_full_unstemmed catena-Poly[[[bis­(3-hy­droxy­adamantane-1-carboxyl­ato-κO (1))(3-hy­droxy­adamantane-1-carb­oxy­lic acid-κO (1))zinc(II)]-μ(2)-4,4′-bipyridine] monohydrate]
title_short catena-Poly[[[bis­(3-hy­droxy­adamantane-1-carboxyl­ato-κO (1))(3-hy­droxy­adamantane-1-carb­oxy­lic acid-κO (1))zinc(II)]-μ(2)-4,4′-bipyridine] monohydrate]
title_sort catena-poly[[[bis­(3-hy­droxy­adamantane-1-carboxyl­ato-κo (1))(3-hy­droxy­adamantane-1-carb­oxy­lic acid-κo (1))zinc(ii)]-μ(2)-4,4′-bipyridine] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120402/
https://www.ncbi.nlm.nih.gov/pubmed/21754615
http://dx.doi.org/10.1107/S1600536811016424
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