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catena-Poly[[[bis(3-hydroxyadamantane-1-carboxylato-κO (1))(3-hydroxyadamantane-1-carboxylic acid-κO (1))zinc(II)]-μ(2)-4,4′-bipyridine] monohydrate]
In the title coordination polymer, {[Zn(C(11)H(15)O(3))(2)(C(10)H(8)N(2))(C(11)H(16)O(3))]·H(2)O}(n), the Zn(II) ion is five coordinated by two N atoms from two 4,4′-bipyridine (4,4′-bpy) molecules and three O atoms from two 3-hydroxyadamantane-1-carboxylate anions (L) and one 3-hydroxyadamant...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120402/ https://www.ncbi.nlm.nih.gov/pubmed/21754615 http://dx.doi.org/10.1107/S1600536811016424 |
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author | Shen, Jin-Bei Guan, Quan-Yin Chen, Xiao-Ju Zhao, Guo-Liang |
author_facet | Shen, Jin-Bei Guan, Quan-Yin Chen, Xiao-Ju Zhao, Guo-Liang |
author_sort | Shen, Jin-Bei |
collection | PubMed |
description | In the title coordination polymer, {[Zn(C(11)H(15)O(3))(2)(C(10)H(8)N(2))(C(11)H(16)O(3))]·H(2)O}(n), the Zn(II) ion is five coordinated by two N atoms from two 4,4′-bipyridine (4,4′-bpy) molecules and three O atoms from two 3-hydroxyadamantane-1-carboxylate anions (L) and one 3-hydroxyadamantane-1-carboxylic acid (HL) molecule. The resulting coordination polyhedron is a near regular ZnN(2)O(3) trigonal bipyramid, with the N atoms in axial sites. The 4,4′-bpy molecules [dihedral angle between the aromatic rings = 17.2 (2)°] act as bridges, connecting the metal ions into an infinite polymeric chain propagating in [[Image: see text]01]. O—H⋯O hydrogen bonds help to consolidate the packing. |
format | Online Article Text |
id | pubmed-3120402 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31204022011-07-13 catena-Poly[[[bis(3-hydroxyadamantane-1-carboxylato-κO (1))(3-hydroxyadamantane-1-carboxylic acid-κO (1))zinc(II)]-μ(2)-4,4′-bipyridine] monohydrate] Shen, Jin-Bei Guan, Quan-Yin Chen, Xiao-Ju Zhao, Guo-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, {[Zn(C(11)H(15)O(3))(2)(C(10)H(8)N(2))(C(11)H(16)O(3))]·H(2)O}(n), the Zn(II) ion is five coordinated by two N atoms from two 4,4′-bipyridine (4,4′-bpy) molecules and three O atoms from two 3-hydroxyadamantane-1-carboxylate anions (L) and one 3-hydroxyadamantane-1-carboxylic acid (HL) molecule. The resulting coordination polyhedron is a near regular ZnN(2)O(3) trigonal bipyramid, with the N atoms in axial sites. The 4,4′-bpy molecules [dihedral angle between the aromatic rings = 17.2 (2)°] act as bridges, connecting the metal ions into an infinite polymeric chain propagating in [[Image: see text]01]. O—H⋯O hydrogen bonds help to consolidate the packing. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120402/ /pubmed/21754615 http://dx.doi.org/10.1107/S1600536811016424 Text en © Shen et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shen, Jin-Bei Guan, Quan-Yin Chen, Xiao-Ju Zhao, Guo-Liang catena-Poly[[[bis(3-hydroxyadamantane-1-carboxylato-κO (1))(3-hydroxyadamantane-1-carboxylic acid-κO (1))zinc(II)]-μ(2)-4,4′-bipyridine] monohydrate] |
title |
catena-Poly[[[bis(3-hydroxyadamantane-1-carboxylato-κO
(1))(3-hydroxyadamantane-1-carboxylic acid-κO
(1))zinc(II)]-μ(2)-4,4′-bipyridine] monohydrate] |
title_full |
catena-Poly[[[bis(3-hydroxyadamantane-1-carboxylato-κO
(1))(3-hydroxyadamantane-1-carboxylic acid-κO
(1))zinc(II)]-μ(2)-4,4′-bipyridine] monohydrate] |
title_fullStr |
catena-Poly[[[bis(3-hydroxyadamantane-1-carboxylato-κO
(1))(3-hydroxyadamantane-1-carboxylic acid-κO
(1))zinc(II)]-μ(2)-4,4′-bipyridine] monohydrate] |
title_full_unstemmed |
catena-Poly[[[bis(3-hydroxyadamantane-1-carboxylato-κO
(1))(3-hydroxyadamantane-1-carboxylic acid-κO
(1))zinc(II)]-μ(2)-4,4′-bipyridine] monohydrate] |
title_short |
catena-Poly[[[bis(3-hydroxyadamantane-1-carboxylato-κO
(1))(3-hydroxyadamantane-1-carboxylic acid-κO
(1))zinc(II)]-μ(2)-4,4′-bipyridine] monohydrate] |
title_sort | catena-poly[[[bis(3-hydroxyadamantane-1-carboxylato-κo
(1))(3-hydroxyadamantane-1-carboxylic acid-κo
(1))zinc(ii)]-μ(2)-4,4′-bipyridine] monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120402/ https://www.ncbi.nlm.nih.gov/pubmed/21754615 http://dx.doi.org/10.1107/S1600536811016424 |
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