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2,5-Bis[4-(dimethyl­amino)­phen­yl]-3,6-dimethyl­pyrazine

The title compound, C(22)H(26)N(4), was prepared from p-dimethyl­amino­propiophenone in six steps. The mol­ecule has no crystallographic symmetry. The dihedral angles between the pyrazine ring and the phenyl rings are 35.81 (6) and 37.11 (8)°. The dimethyl­amino groups are essentially planar (sum of...

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Detalles Bibliográficos
Autores principales: Moschel, Sebastian, Schollmeyer, Dieter, Detert, Heiner
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120404/
https://www.ncbi.nlm.nih.gov/pubmed/21754805
http://dx.doi.org/10.1107/S160053681101748X
Descripción
Sumario:The title compound, C(22)H(26)N(4), was prepared from p-dimethyl­amino­propiophenone in six steps. The mol­ecule has no crystallographic symmetry. The dihedral angles between the pyrazine ring and the phenyl rings are 35.81 (6) and 37.11 (8)°. The dimethyl­amino groups are essentially planar (sum of the bond angles at N = 359.3 and 359.9°) and nearly coplanar with the adjacent aromatic ring [dihedral angles = 5.54 (11) and 7.40 (3)°]. This effect and the short aniline C—N bonds can be rationalised in terms of charge transfer from the amino groups to the central pyrazine ring.