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Silver(I) diaquamagnesium catena-borodiphosphate(V) monohydrate, AgMg(H(2)O)(2)[BP(2)O(8)]·H(2)O
The title compound contains infinite one-dimensional [BP(2)O(8)](3−) borophosphate helical ribbons, built up from alternate BO(4) and PO(4) tetrahedra arranged around the 6(5) screw axes. The vertex-sharing BO(4) and PO(4) tetrahedra form a spiral ribbon of four-membered rings in which BO(4) and P...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120408/ https://www.ncbi.nlm.nih.gov/pubmed/21754567 http://dx.doi.org/10.1107/S1600536811019477 |
Sumario: | The title compound contains infinite one-dimensional [BP(2)O(8)](3−) borophosphate helical ribbons, built up from alternate BO(4) and PO(4) tetrahedra arranged around the 6(5) screw axes. The vertex-sharing BO(4) and PO(4) tetrahedra form a spiral ribbon of four-membered rings in which BO(4) and PO(4) groups alternate. The ribbons are connected through slightly distorted MgO(4)(H(2)O)(2) octahedra, in which the four O atoms belong to the phosphate groups. The free threads of the helices are occupied by silver ions, which are in an irregular environment surrounded by six O atoms. The central channels of the helices, running along the c axis, are filled with the water molecules. The structure is stabilized by O—H⋯O hydrogen bonds between the water molecules and O atoms that are part of the helices. The crystal structure of the title compound is isotopic with other analogous borophosphates such as A (I) M (II)(H(2)O)(2)[BP(2)O(8)]·H(2)O, where A (I) = Li, Na, K or NH(4) (+) and M (II) = Mg, Mn, Fe, Co, Ni, Cu, Zn or Cd. |
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