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Silver(I) diaqua­magnesium catena-borodiphosphate(V) monohydrate, AgMg(H(2)O)(2)[BP(2)O(8)]·H(2)O

The title compound contains infinite one-dimensional [BP(2)O(8)](3−) borophosphate helical ribbons, built up from alternate BO(4) and PO(4) tetra­hedra arranged around the 6(5) screw axes. The vertex-sharing BO(4) and PO(4) tetra­hedra form a spiral ribbon of four-membered rings in which BO(4) and P...

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Autores principales: Zouihri, Hafid, Saadi, Mohammed, Jaber, Boujemaa, El Ammari, Lehcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120408/
https://www.ncbi.nlm.nih.gov/pubmed/21754567
http://dx.doi.org/10.1107/S1600536811019477
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author Zouihri, Hafid
Saadi, Mohammed
Jaber, Boujemaa
El Ammari, Lehcen
author_facet Zouihri, Hafid
Saadi, Mohammed
Jaber, Boujemaa
El Ammari, Lehcen
author_sort Zouihri, Hafid
collection PubMed
description The title compound contains infinite one-dimensional [BP(2)O(8)](3−) borophosphate helical ribbons, built up from alternate BO(4) and PO(4) tetra­hedra arranged around the 6(5) screw axes. The vertex-sharing BO(4) and PO(4) tetra­hedra form a spiral ribbon of four-membered rings in which BO(4) and PO(4) groups alternate. The ribbons are connected through slightly distorted MgO(4)(H(2)O)(2) octa­hedra, in which the four O atoms belong to the phosphate groups. The free threads of the helices are occupied by silver ions, which are in an irregular environment surrounded by six O atoms. The central channels of the helices, running along the c axis, are filled with the water mol­ecules. The structure is stabilized by O—H⋯O hydrogen bonds between the water mol­ecules and O atoms that are part of the helices. The crystal structure of the title compound is isotopic with other analogous borophosphates such as A (I) M (II)(H(2)O)(2)[BP(2)O(8)]·H(2)O, where A (I) = Li, Na, K or NH(4) (+) and M (II) = Mg, Mn, Fe, Co, Ni, Cu, Zn or Cd.
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spelling pubmed-31204082011-07-13 Silver(I) diaqua­magnesium catena-borodiphosphate(V) monohydrate, AgMg(H(2)O)(2)[BP(2)O(8)]·H(2)O Zouihri, Hafid Saadi, Mohammed Jaber, Boujemaa El Ammari, Lehcen Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title compound contains infinite one-dimensional [BP(2)O(8)](3−) borophosphate helical ribbons, built up from alternate BO(4) and PO(4) tetra­hedra arranged around the 6(5) screw axes. The vertex-sharing BO(4) and PO(4) tetra­hedra form a spiral ribbon of four-membered rings in which BO(4) and PO(4) groups alternate. The ribbons are connected through slightly distorted MgO(4)(H(2)O)(2) octa­hedra, in which the four O atoms belong to the phosphate groups. The free threads of the helices are occupied by silver ions, which are in an irregular environment surrounded by six O atoms. The central channels of the helices, running along the c axis, are filled with the water mol­ecules. The structure is stabilized by O—H⋯O hydrogen bonds between the water mol­ecules and O atoms that are part of the helices. The crystal structure of the title compound is isotopic with other analogous borophosphates such as A (I) M (II)(H(2)O)(2)[BP(2)O(8)]·H(2)O, where A (I) = Li, Na, K or NH(4) (+) and M (II) = Mg, Mn, Fe, Co, Ni, Cu, Zn or Cd. International Union of Crystallography 2011-05-28 /pmc/articles/PMC3120408/ /pubmed/21754567 http://dx.doi.org/10.1107/S1600536811019477 Text en © Zouihri et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Zouihri, Hafid
Saadi, Mohammed
Jaber, Boujemaa
El Ammari, Lehcen
Silver(I) diaqua­magnesium catena-borodiphosphate(V) monohydrate, AgMg(H(2)O)(2)[BP(2)O(8)]·H(2)O
title Silver(I) diaqua­magnesium catena-borodiphosphate(V) monohydrate, AgMg(H(2)O)(2)[BP(2)O(8)]·H(2)O
title_full Silver(I) diaqua­magnesium catena-borodiphosphate(V) monohydrate, AgMg(H(2)O)(2)[BP(2)O(8)]·H(2)O
title_fullStr Silver(I) diaqua­magnesium catena-borodiphosphate(V) monohydrate, AgMg(H(2)O)(2)[BP(2)O(8)]·H(2)O
title_full_unstemmed Silver(I) diaqua­magnesium catena-borodiphosphate(V) monohydrate, AgMg(H(2)O)(2)[BP(2)O(8)]·H(2)O
title_short Silver(I) diaqua­magnesium catena-borodiphosphate(V) monohydrate, AgMg(H(2)O)(2)[BP(2)O(8)]·H(2)O
title_sort silver(i) diaqua­magnesium catena-borodiphosphate(v) monohydrate, agmg(h(2)o)(2)[bp(2)o(8)]·h(2)o
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120408/
https://www.ncbi.nlm.nih.gov/pubmed/21754567
http://dx.doi.org/10.1107/S1600536811019477
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