Ammonium 4,6-dioxo-2-sulfanylidene-1,3-diazinan-5-ide

In the title salt, NH(4) (+)·C(4)H(3)N(2)O(2)S(−), the asymmetric unit comprises two half-occupied ammonium positions and a 4,6-dioxo-2-sulfanylidene-1,3-diazinan-5-ide anion. The anion shows C (2) as well as C (s) symmetry and is present in its diketonic tautomeric form. Intra­cyclic angles span a...

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Detalles Bibliográficos
Autores principales: Betz, Richard, Gerber, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120410/
https://www.ncbi.nlm.nih.gov/pubmed/21754723
http://dx.doi.org/10.1107/S1600536811016722
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author Betz, Richard
Gerber, Thomas
author_facet Betz, Richard
Gerber, Thomas
author_sort Betz, Richard
collection PubMed
description In the title salt, NH(4) (+)·C(4)H(3)N(2)O(2)S(−), the asymmetric unit comprises two half-occupied ammonium positions and a 4,6-dioxo-2-sulfanylidene-1,3-diazinan-5-ide anion. The anion shows C (2) as well as C (s) symmetry and is present in its diketonic tautomeric form. Intra­cyclic angles span a range from 116.64 (9)–124.67 (9)°. Inter­molecular N—H⋯O hydrogen bonds connect the cations and anions to form a three-dimensional network.
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spelling pubmed-31204102011-07-13 Ammonium 4,6-dioxo-2-sulfanylidene-1,3-diazinan-5-ide Betz, Richard Gerber, Thomas Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, NH(4) (+)·C(4)H(3)N(2)O(2)S(−), the asymmetric unit comprises two half-occupied ammonium positions and a 4,6-dioxo-2-sulfanylidene-1,3-diazinan-5-ide anion. The anion shows C (2) as well as C (s) symmetry and is present in its diketonic tautomeric form. Intra­cyclic angles span a range from 116.64 (9)–124.67 (9)°. Inter­molecular N—H⋯O hydrogen bonds connect the cations and anions to form a three-dimensional network. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120410/ /pubmed/21754723 http://dx.doi.org/10.1107/S1600536811016722 Text en © Betz and Gerber 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Betz, Richard
Gerber, Thomas
Ammonium 4,6-dioxo-2-sulfanylidene-1,3-diazinan-5-ide
title Ammonium 4,6-dioxo-2-sulfanylidene-1,3-diazinan-5-ide
title_full Ammonium 4,6-dioxo-2-sulfanylidene-1,3-diazinan-5-ide
title_fullStr Ammonium 4,6-dioxo-2-sulfanylidene-1,3-diazinan-5-ide
title_full_unstemmed Ammonium 4,6-dioxo-2-sulfanylidene-1,3-diazinan-5-ide
title_short Ammonium 4,6-dioxo-2-sulfanylidene-1,3-diazinan-5-ide
title_sort ammonium 4,6-dioxo-2-sulfanylidene-1,3-diazinan-5-ide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120410/
https://www.ncbi.nlm.nih.gov/pubmed/21754723
http://dx.doi.org/10.1107/S1600536811016722
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AT gerberthomas ammonium46dioxo2sulfanylidene13diazinan5ide

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