{N,N′-[2,2′-(Ethane-1,2-diyldisulfanediyl)di-o-phenyl­ene]bis­(quinoline-2-carboxamidato)}copper(II)

In the title compound, [Cu(C(34)H(24)N(4)O(2)S(2))] or [Cu(bqdapte)], where H(2)bqdapte is 1,2-{bis­[2-(quinoline-2-carboxamido)­phen­yl]sulfan­yl}ethane, the Cu(II) ion is coordinated to the dianionic hexa­dentate bqdapte(2−) ligand by two amide and two quinoline N atoms and two thio­ether S atoms....

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Detalles Bibliográficos
Autores principales: Meghdadi, Soraia, Mirkhani, Valiollah, Ford, Peter C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120416/
https://www.ncbi.nlm.nih.gov/pubmed/21754691
http://dx.doi.org/10.1107/S1600536811019581
Descripción
Sumario:In the title compound, [Cu(C(34)H(24)N(4)O(2)S(2))] or [Cu(bqdapte)], where H(2)bqdapte is 1,2-{bis­[2-(quinoline-2-carboxamido)­phen­yl]sulfan­yl}ethane, the Cu(II) ion is coordinated to the dianionic hexa­dentate bqdapte(2−) ligand by two amide and two quinoline N atoms and two thio­ether S atoms. In the observed conformation of the hexa­dentate ligand, the quinoline rings attain positions related by a twofold axis. The Cu atom displays a Jahn–Teller-distorted octa­hedral CuN(4)S(2) geometry axially compressed along the two trans-configured Cu—N(amidate) bonds.

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