{N,N′-[2,2′-(Ethane-1,2-diyldisulfanediyl)di-o-phenyl­ene]bis­(quinoline-2-carboxamidato)}copper(II)

In the title compound, [Cu(C(34)H(24)N(4)O(2)S(2))] or [Cu(bqdapte)], where H(2)bqdapte is 1,2-{bis­[2-(quinoline-2-carboxamido)­phen­yl]sulfan­yl}ethane, the Cu(II) ion is coordinated to the dianionic hexa­dentate bqdapte(2−) ligand by two amide and two quinoline N atoms and two thio­ether S atoms....

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Detalles Bibliográficos
Autores principales: Meghdadi, Soraia, Mirkhani, Valiollah, Ford, Peter C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120416/
https://www.ncbi.nlm.nih.gov/pubmed/21754691
http://dx.doi.org/10.1107/S1600536811019581
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author Meghdadi, Soraia
Mirkhani, Valiollah
Ford, Peter C.
author_facet Meghdadi, Soraia
Mirkhani, Valiollah
Ford, Peter C.
author_sort Meghdadi, Soraia
collection PubMed
description In the title compound, [Cu(C(34)H(24)N(4)O(2)S(2))] or [Cu(bqdapte)], where H(2)bqdapte is 1,2-{bis­[2-(quinoline-2-carboxamido)­phen­yl]sulfan­yl}ethane, the Cu(II) ion is coordinated to the dianionic hexa­dentate bqdapte(2−) ligand by two amide and two quinoline N atoms and two thio­ether S atoms. In the observed conformation of the hexa­dentate ligand, the quinoline rings attain positions related by a twofold axis. The Cu atom displays a Jahn–Teller-distorted octa­hedral CuN(4)S(2) geometry axially compressed along the two trans-configured Cu—N(amidate) bonds.
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spelling pubmed-31204162011-07-13 {N,N′-[2,2′-(Ethane-1,2-diyldisulfanediyl)di-o-phenyl­ene]bis­(quinoline-2-carboxamidato)}copper(II) Meghdadi, Soraia Mirkhani, Valiollah Ford, Peter C. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(34)H(24)N(4)O(2)S(2))] or [Cu(bqdapte)], where H(2)bqdapte is 1,2-{bis­[2-(quinoline-2-carboxamido)­phen­yl]sulfan­yl}ethane, the Cu(II) ion is coordinated to the dianionic hexa­dentate bqdapte(2−) ligand by two amide and two quinoline N atoms and two thio­ether S atoms. In the observed conformation of the hexa­dentate ligand, the quinoline rings attain positions related by a twofold axis. The Cu atom displays a Jahn–Teller-distorted octa­hedral CuN(4)S(2) geometry axially compressed along the two trans-configured Cu—N(amidate) bonds. International Union of Crystallography 2011-05-28 /pmc/articles/PMC3120416/ /pubmed/21754691 http://dx.doi.org/10.1107/S1600536811019581 Text en © Meghdadi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Meghdadi, Soraia
Mirkhani, Valiollah
Ford, Peter C.
{N,N′-[2,2′-(Ethane-1,2-diyldisulfanediyl)di-o-phenyl­ene]bis­(quinoline-2-carboxamidato)}copper(II)
title {N,N′-[2,2′-(Ethane-1,2-diyldisulfanediyl)di-o-phenyl­ene]bis­(quinoline-2-carboxamidato)}copper(II)
title_full {N,N′-[2,2′-(Ethane-1,2-diyldisulfanediyl)di-o-phenyl­ene]bis­(quinoline-2-carboxamidato)}copper(II)
title_fullStr {N,N′-[2,2′-(Ethane-1,2-diyldisulfanediyl)di-o-phenyl­ene]bis­(quinoline-2-carboxamidato)}copper(II)
title_full_unstemmed {N,N′-[2,2′-(Ethane-1,2-diyldisulfanediyl)di-o-phenyl­ene]bis­(quinoline-2-carboxamidato)}copper(II)
title_short {N,N′-[2,2′-(Ethane-1,2-diyldisulfanediyl)di-o-phenyl­ene]bis­(quinoline-2-carboxamidato)}copper(II)
title_sort {n,n′-[2,2′-(ethane-1,2-diyldisulfanediyl)di-o-phenyl­ene]bis­(quinoline-2-carboxamidato)}copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120416/
https://www.ncbi.nlm.nih.gov/pubmed/21754691
http://dx.doi.org/10.1107/S1600536811019581
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AT fordpeterc nn22ethane12diyldisulfanediyldiophenylenebisquinoline2carboxamidatocopperii

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