cis-Bis(2,2′-bipyridine-κ(2) N,N′)dichlorido­iron(III) perchlorate

In the crystal structure of the title compound, [FeCl(2)(C(10)H(8)N(2))(2)]ClO(4), the coordination around the Fe(III) atom is approximately octa­hedral. The equatorial positions are occupied by two N atoms from two 2,2′-bipyridyl ligands [Fe—N = 2.121 (5) and 2.147 (5) Å] and two Cl atoms [Fe—Cl =...

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Autor principal: Zhang, Zhi-Fang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120418/
https://www.ncbi.nlm.nih.gov/pubmed/21754585
http://dx.doi.org/10.1107/S1600536811016035
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author Zhang, Zhi-Fang
author_facet Zhang, Zhi-Fang
author_sort Zhang, Zhi-Fang
collection PubMed
description In the crystal structure of the title compound, [FeCl(2)(C(10)H(8)N(2))(2)]ClO(4), the coordination around the Fe(III) atom is approximately octa­hedral. The equatorial positions are occupied by two N atoms from two 2,2′-bipyridyl ligands [Fe—N = 2.121 (5) and 2.147 (5) Å] and two Cl atoms [Fe—Cl = 2.220 (2) and 2.2074 (18) Å]. Weak inter­molecular C—H⋯O and C—H⋯Cl hydrogen bonds and C—H⋯π inter­actions consolidate the crystal packing.
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spelling pubmed-31204182011-07-13 cis-Bis(2,2′-bipyridine-κ(2) N,N′)dichlorido­iron(III) perchlorate Zhang, Zhi-Fang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [FeCl(2)(C(10)H(8)N(2))(2)]ClO(4), the coordination around the Fe(III) atom is approximately octa­hedral. The equatorial positions are occupied by two N atoms from two 2,2′-bipyridyl ligands [Fe—N = 2.121 (5) and 2.147 (5) Å] and two Cl atoms [Fe—Cl = 2.220 (2) and 2.2074 (18) Å]. Weak inter­molecular C—H⋯O and C—H⋯Cl hydrogen bonds and C—H⋯π inter­actions consolidate the crystal packing. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120418/ /pubmed/21754585 http://dx.doi.org/10.1107/S1600536811016035 Text en © Zhi-Fang Zhang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Zhi-Fang
cis-Bis(2,2′-bipyridine-κ(2) N,N′)dichlorido­iron(III) perchlorate
title cis-Bis(2,2′-bipyridine-κ(2) N,N′)dichlorido­iron(III) perchlorate
title_full cis-Bis(2,2′-bipyridine-κ(2) N,N′)dichlorido­iron(III) perchlorate
title_fullStr cis-Bis(2,2′-bipyridine-κ(2) N,N′)dichlorido­iron(III) perchlorate
title_full_unstemmed cis-Bis(2,2′-bipyridine-κ(2) N,N′)dichlorido­iron(III) perchlorate
title_short cis-Bis(2,2′-bipyridine-κ(2) N,N′)dichlorido­iron(III) perchlorate
title_sort cis-bis(2,2′-bipyridine-κ(2) n,n′)dichlorido­iron(iii) perchlorate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120418/
https://www.ncbi.nlm.nih.gov/pubmed/21754585
http://dx.doi.org/10.1107/S1600536811016035
work_keys_str_mv AT zhangzhifang cisbis22bipyridinek2nndichloridoironiiiperchlorate

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