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Bis[μ-1,2-bis(1H-imidazol-1-ylmethyl)benzene-κ(2) N (3):N (3′)]disilver(I) bis(4-carboxynaphthalene-1-carboxylate) tetrahydrate
In the title compound, [Ag(2)(C(14)H(14)N(4))(2)](C(12)H(7)O(4))(2)·4H(2)O, the dinuclear dication has crystallographically imposed inversion symmetry. Each Ag(I) ion is bicoordinated in a slightly distorted linear coordination geometry by the N atoms of two ligands, resulting in the formation of a...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120420/ https://www.ncbi.nlm.nih.gov/pubmed/21754678 http://dx.doi.org/10.1107/S1600536811018691 |
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author | Yang, Yan Yuan, Guohui |
author_facet | Yang, Yan Yuan, Guohui |
author_sort | Yang, Yan |
collection | PubMed |
description | In the title compound, [Ag(2)(C(14)H(14)N(4))(2)](C(12)H(7)O(4))(2)·4H(2)O, the dinuclear dication has crystallographically imposed inversion symmetry. Each Ag(I) ion is bicoordinated in a slightly distorted linear coordination geometry by the N atoms of two ligands, resulting in the formation of a 22-membered metallamacrocycle. In the dication, π–π interactions are observed between the imidazole rings, with centroid–centroid distances of 3.528 (3) Å and dihedral angles of 9.92 (9)°. The crystal structure is stabilized by intermolecular O—H⋯O hydrogen bonds and π–π interactions involving the benzene rings of adjacent dications, with centroid–centroid distances of 3.651 (2) Å. |
format | Online Article Text |
id | pubmed-3120420 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31204202011-07-13 Bis[μ-1,2-bis(1H-imidazol-1-ylmethyl)benzene-κ(2) N (3):N (3′)]disilver(I) bis(4-carboxynaphthalene-1-carboxylate) tetrahydrate Yang, Yan Yuan, Guohui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ag(2)(C(14)H(14)N(4))(2)](C(12)H(7)O(4))(2)·4H(2)O, the dinuclear dication has crystallographically imposed inversion symmetry. Each Ag(I) ion is bicoordinated in a slightly distorted linear coordination geometry by the N atoms of two ligands, resulting in the formation of a 22-membered metallamacrocycle. In the dication, π–π interactions are observed between the imidazole rings, with centroid–centroid distances of 3.528 (3) Å and dihedral angles of 9.92 (9)°. The crystal structure is stabilized by intermolecular O—H⋯O hydrogen bonds and π–π interactions involving the benzene rings of adjacent dications, with centroid–centroid distances of 3.651 (2) Å. International Union of Crystallography 2011-05-25 /pmc/articles/PMC3120420/ /pubmed/21754678 http://dx.doi.org/10.1107/S1600536811018691 Text en © Yang and Yuan 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yang, Yan Yuan, Guohui Bis[μ-1,2-bis(1H-imidazol-1-ylmethyl)benzene-κ(2) N (3):N (3′)]disilver(I) bis(4-carboxynaphthalene-1-carboxylate) tetrahydrate |
title | Bis[μ-1,2-bis(1H-imidazol-1-ylmethyl)benzene-κ(2)
N
(3):N
(3′)]disilver(I) bis(4-carboxynaphthalene-1-carboxylate) tetrahydrate |
title_full | Bis[μ-1,2-bis(1H-imidazol-1-ylmethyl)benzene-κ(2)
N
(3):N
(3′)]disilver(I) bis(4-carboxynaphthalene-1-carboxylate) tetrahydrate |
title_fullStr | Bis[μ-1,2-bis(1H-imidazol-1-ylmethyl)benzene-κ(2)
N
(3):N
(3′)]disilver(I) bis(4-carboxynaphthalene-1-carboxylate) tetrahydrate |
title_full_unstemmed | Bis[μ-1,2-bis(1H-imidazol-1-ylmethyl)benzene-κ(2)
N
(3):N
(3′)]disilver(I) bis(4-carboxynaphthalene-1-carboxylate) tetrahydrate |
title_short | Bis[μ-1,2-bis(1H-imidazol-1-ylmethyl)benzene-κ(2)
N
(3):N
(3′)]disilver(I) bis(4-carboxynaphthalene-1-carboxylate) tetrahydrate |
title_sort | bis[μ-1,2-bis(1h-imidazol-1-ylmethyl)benzene-κ(2)
n
(3):n
(3′)]disilver(i) bis(4-carboxynaphthalene-1-carboxylate) tetrahydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120420/ https://www.ncbi.nlm.nih.gov/pubmed/21754678 http://dx.doi.org/10.1107/S1600536811018691 |
work_keys_str_mv | AT yangyan bism12bis1himidazol1ylmethylbenzenek2n3n3disilveribis4carboxynaphthalene1carboxylatetetrahydrate AT yuanguohui bism12bis1himidazol1ylmethylbenzenek2n3n3disilveribis4carboxynaphthalene1carboxylatetetrahydrate |