Cargando…

Bis[μ-1,2-bis­(1H-imidazol-1-ylmeth­yl)benzene-κ(2) N (3):N (3′)]disilver(I) bis­(4-carb­oxy­naphthalene-1-carboxyl­ate) tetra­hydrate

In the title compound, [Ag(2)(C(14)H(14)N(4))(2)](C(12)H(7)O(4))(2)·4H(2)O, the dinuclear dication has crystallographically imposed inversion symmetry. Each Ag(I) ion is bicoordinated in a slightly distorted linear coordination geometry by the N atoms of two ligands, resulting in the formation of a...

Descripción completa

Detalles Bibliográficos
Autores principales: Yang, Yan, Yuan, Guohui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120420/
https://www.ncbi.nlm.nih.gov/pubmed/21754678
http://dx.doi.org/10.1107/S1600536811018691
_version_ 1782206675284918272
author Yang, Yan
Yuan, Guohui
author_facet Yang, Yan
Yuan, Guohui
author_sort Yang, Yan
collection PubMed
description In the title compound, [Ag(2)(C(14)H(14)N(4))(2)](C(12)H(7)O(4))(2)·4H(2)O, the dinuclear dication has crystallographically imposed inversion symmetry. Each Ag(I) ion is bicoordinated in a slightly distorted linear coordination geometry by the N atoms of two ligands, resulting in the formation of a 22-membered metallamacrocycle. In the dication, π–π inter­actions are observed between the imidazole rings, with centroid–centroid distances of 3.528 (3) Å and dihedral angles of 9.92 (9)°. The crystal structure is stabilized by inter­molecular O—H⋯O hydrogen bonds and π–π inter­actions involving the benzene rings of adjacent dications, with centroid–centroid distances of 3.651 (2) Å.
format Online
Article
Text
id pubmed-3120420
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-31204202011-07-13 Bis[μ-1,2-bis­(1H-imidazol-1-ylmeth­yl)benzene-κ(2) N (3):N (3′)]disilver(I) bis­(4-carb­oxy­naphthalene-1-carboxyl­ate) tetra­hydrate Yang, Yan Yuan, Guohui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ag(2)(C(14)H(14)N(4))(2)](C(12)H(7)O(4))(2)·4H(2)O, the dinuclear dication has crystallographically imposed inversion symmetry. Each Ag(I) ion is bicoordinated in a slightly distorted linear coordination geometry by the N atoms of two ligands, resulting in the formation of a 22-membered metallamacrocycle. In the dication, π–π inter­actions are observed between the imidazole rings, with centroid–centroid distances of 3.528 (3) Å and dihedral angles of 9.92 (9)°. The crystal structure is stabilized by inter­molecular O—H⋯O hydrogen bonds and π–π inter­actions involving the benzene rings of adjacent dications, with centroid–centroid distances of 3.651 (2) Å. International Union of Crystallography 2011-05-25 /pmc/articles/PMC3120420/ /pubmed/21754678 http://dx.doi.org/10.1107/S1600536811018691 Text en © Yang and Yuan 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Yan
Yuan, Guohui
Bis[μ-1,2-bis­(1H-imidazol-1-ylmeth­yl)benzene-κ(2) N (3):N (3′)]disilver(I) bis­(4-carb­oxy­naphthalene-1-carboxyl­ate) tetra­hydrate
title Bis[μ-1,2-bis­(1H-imidazol-1-ylmeth­yl)benzene-κ(2) N (3):N (3′)]disilver(I) bis­(4-carb­oxy­naphthalene-1-carboxyl­ate) tetra­hydrate
title_full Bis[μ-1,2-bis­(1H-imidazol-1-ylmeth­yl)benzene-κ(2) N (3):N (3′)]disilver(I) bis­(4-carb­oxy­naphthalene-1-carboxyl­ate) tetra­hydrate
title_fullStr Bis[μ-1,2-bis­(1H-imidazol-1-ylmeth­yl)benzene-κ(2) N (3):N (3′)]disilver(I) bis­(4-carb­oxy­naphthalene-1-carboxyl­ate) tetra­hydrate
title_full_unstemmed Bis[μ-1,2-bis­(1H-imidazol-1-ylmeth­yl)benzene-κ(2) N (3):N (3′)]disilver(I) bis­(4-carb­oxy­naphthalene-1-carboxyl­ate) tetra­hydrate
title_short Bis[μ-1,2-bis­(1H-imidazol-1-ylmeth­yl)benzene-κ(2) N (3):N (3′)]disilver(I) bis­(4-carb­oxy­naphthalene-1-carboxyl­ate) tetra­hydrate
title_sort bis[μ-1,2-bis­(1h-imidazol-1-ylmeth­yl)benzene-κ(2) n (3):n (3′)]disilver(i) bis­(4-carb­oxy­naphthalene-1-carboxyl­ate) tetra­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120420/
https://www.ncbi.nlm.nih.gov/pubmed/21754678
http://dx.doi.org/10.1107/S1600536811018691
work_keys_str_mv AT yangyan bism12bis1himidazol1ylmethylbenzenek2n3n3disilveribis4carboxynaphthalene1carboxylatetetrahydrate
AT yuanguohui bism12bis1himidazol1ylmethylbenzenek2n3n3disilveribis4carboxynaphthalene1carboxylatetetrahydrate