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Aqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ(4) O,N,N′,O′}(formato-κO)manganese(III) dihydrate
The Mn(III) atom in the title complex, [Mn(C(18)H(18)N(2)O(4))(CHO(2))(H(2)O)]·2H(2)O, is O,N,N′,O′-chelated by the deprotonated Schiff base; the four chelating atoms form an approximate square, with the O atoms of the water molecule and the formate ion in axial positions above and below the squar...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120422/ https://www.ncbi.nlm.nih.gov/pubmed/21754637 http://dx.doi.org/10.1107/S1600536811017648 |
| _version_ | 1782206675754680320 |
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| author | Lee, See Mun Lo, Kong Mun Ng, Seik Weng |
| author_facet | Lee, See Mun Lo, Kong Mun Ng, Seik Weng |
| author_sort | Lee, See Mun |
| collection | PubMed |
| description | The Mn(III) atom in the title complex, [Mn(C(18)H(18)N(2)O(4))(CHO(2))(H(2)O)]·2H(2)O, is O,N,N′,O′-chelated by the deprotonated Schiff base; the four chelating atoms form an approximate square, with the O atoms of the water molecule and the formate ion in axial positions above and below the square plane. Two metal-bearing molecules are linked by an O—H(water)⋯O hydrogen bond about a center of inversion, generating a hydrogen-bonded dinuclear species; adjacent dinuclear units are linked through the lattice water molecules, forming a three-dimensional network. |
| format | Online Article Text |
| id | pubmed-3120422 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-31204222011-07-13 Aqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ(4) O,N,N′,O′}(formato-κO)manganese(III) dihydrate Lee, See Mun Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Mn(III) atom in the title complex, [Mn(C(18)H(18)N(2)O(4))(CHO(2))(H(2)O)]·2H(2)O, is O,N,N′,O′-chelated by the deprotonated Schiff base; the four chelating atoms form an approximate square, with the O atoms of the water molecule and the formate ion in axial positions above and below the square plane. Two metal-bearing molecules are linked by an O—H(water)⋯O hydrogen bond about a center of inversion, generating a hydrogen-bonded dinuclear species; adjacent dinuclear units are linked through the lattice water molecules, forming a three-dimensional network. International Union of Crystallography 2011-05-14 /pmc/articles/PMC3120422/ /pubmed/21754637 http://dx.doi.org/10.1107/S1600536811017648 Text en © Lee et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Lee, See Mun Lo, Kong Mun Ng, Seik Weng Aqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ(4) O,N,N′,O′}(formato-κO)manganese(III) dihydrate |
| title | Aqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ(4)
O,N,N′,O′}(formato-κO)manganese(III) dihydrate |
| title_full | Aqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ(4)
O,N,N′,O′}(formato-κO)manganese(III) dihydrate |
| title_fullStr | Aqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ(4)
O,N,N′,O′}(formato-κO)manganese(III) dihydrate |
| title_full_unstemmed | Aqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ(4)
O,N,N′,O′}(formato-κO)manganese(III) dihydrate |
| title_short | Aqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ(4)
O,N,N′,O′}(formato-κO)manganese(III) dihydrate |
| title_sort | aqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ(4)
o,n,n′,o′}(formato-κo)manganese(iii) dihydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120422/ https://www.ncbi.nlm.nih.gov/pubmed/21754637 http://dx.doi.org/10.1107/S1600536811017648 |
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