Bis(2-amino-1,3-benzothia­zol-3-ium) tetra­chloridozincate(II)

The asymmetric unit of the title compound, (C(7)H(7)N(2)S)(2)[ZnCl(4)], contains a network of 2-amino­benzothia­zolium cations and tetra­hedral [ZnCl(4)](2−) anions. The crystal packing is influenced by cation-to-anion N—H⋯Cl and C—H⋯Cl hydrogen bonds. The [ZnCl(4)](2−) anions have a distorded tetra...

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Detalles Bibliográficos
Autores principales: Kefi, Riadh, Jeanneau, Erwann, Lefebvre, Frédéric, Ben Nasr, Cherif
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120423/
https://www.ncbi.nlm.nih.gov/pubmed/21754568
http://dx.doi.org/10.1107/S1600536811015753
Descripción
Sumario:The asymmetric unit of the title compound, (C(7)H(7)N(2)S)(2)[ZnCl(4)], contains a network of 2-amino­benzothia­zolium cations and tetra­hedral [ZnCl(4)](2−) anions. The crystal packing is influenced by cation-to-anion N—H⋯Cl and C—H⋯Cl hydrogen bonds. The [ZnCl(4)](2−) anions have a distorded tetra­hedral geometry. Inter­molecular π–π stacking inter­actions are present between neighboring benzene rings, thia­zole and benzene rings and neighboring thia­zole rings [centroid–centroid distances = 3.711 (2), 3.554 (1), 3.536 (2) and 3.572 (1) Å].

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