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Bis(2-amino-1,3-benzothiazol-3-ium) tetrachloridozincate(II)
The asymmetric unit of the title compound, (C(7)H(7)N(2)S)(2)[ZnCl(4)], contains a network of 2-aminobenzothiazolium cations and tetrahedral [ZnCl(4)](2−) anions. The crystal packing is influenced by cation-to-anion N—H⋯Cl and C—H⋯Cl hydrogen bonds. The [ZnCl(4)](2−) anions have a distorded tetra...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120423/ https://www.ncbi.nlm.nih.gov/pubmed/21754568 http://dx.doi.org/10.1107/S1600536811015753 |
Sumario: | The asymmetric unit of the title compound, (C(7)H(7)N(2)S)(2)[ZnCl(4)], contains a network of 2-aminobenzothiazolium cations and tetrahedral [ZnCl(4)](2−) anions. The crystal packing is influenced by cation-to-anion N—H⋯Cl and C—H⋯Cl hydrogen bonds. The [ZnCl(4)](2−) anions have a distorded tetrahedral geometry. Intermolecular π–π stacking interactions are present between neighboring benzene rings, thiazole and benzene rings and neighboring thiazole rings [centroid–centroid distances = 3.711 (2), 3.554 (1), 3.536 (2) and 3.572 (1) Å]. |
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