Bis(2-amino-1,3-benzothia­zol-3-ium) tetra­chloridozincate(II)

The asymmetric unit of the title compound, (C(7)H(7)N(2)S)(2)[ZnCl(4)], contains a network of 2-amino­benzothia­zolium cations and tetra­hedral [ZnCl(4)](2−) anions. The crystal packing is influenced by cation-to-anion N—H⋯Cl and C—H⋯Cl hydrogen bonds. The [ZnCl(4)](2−) anions have a distorded tetra...

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Detalles Bibliográficos
Autores principales: Kefi, Riadh, Jeanneau, Erwann, Lefebvre, Frédéric, Ben Nasr, Cherif
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120423/
https://www.ncbi.nlm.nih.gov/pubmed/21754568
http://dx.doi.org/10.1107/S1600536811015753
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author Kefi, Riadh
Jeanneau, Erwann
Lefebvre, Frédéric
Ben Nasr, Cherif
author_facet Kefi, Riadh
Jeanneau, Erwann
Lefebvre, Frédéric
Ben Nasr, Cherif
author_sort Kefi, Riadh
collection PubMed
description The asymmetric unit of the title compound, (C(7)H(7)N(2)S)(2)[ZnCl(4)], contains a network of 2-amino­benzothia­zolium cations and tetra­hedral [ZnCl(4)](2−) anions. The crystal packing is influenced by cation-to-anion N—H⋯Cl and C—H⋯Cl hydrogen bonds. The [ZnCl(4)](2−) anions have a distorded tetra­hedral geometry. Inter­molecular π–π stacking inter­actions are present between neighboring benzene rings, thia­zole and benzene rings and neighboring thia­zole rings [centroid–centroid distances = 3.711 (2), 3.554 (1), 3.536 (2) and 3.572 (1) Å].
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spelling pubmed-31204232011-07-13 Bis(2-amino-1,3-benzothia­zol-3-ium) tetra­chloridozincate(II) Kefi, Riadh Jeanneau, Erwann Lefebvre, Frédéric Ben Nasr, Cherif Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(7)H(7)N(2)S)(2)[ZnCl(4)], contains a network of 2-amino­benzothia­zolium cations and tetra­hedral [ZnCl(4)](2−) anions. The crystal packing is influenced by cation-to-anion N—H⋯Cl and C—H⋯Cl hydrogen bonds. The [ZnCl(4)](2−) anions have a distorded tetra­hedral geometry. Inter­molecular π–π stacking inter­actions are present between neighboring benzene rings, thia­zole and benzene rings and neighboring thia­zole rings [centroid–centroid distances = 3.711 (2), 3.554 (1), 3.536 (2) and 3.572 (1) Å]. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120423/ /pubmed/21754568 http://dx.doi.org/10.1107/S1600536811015753 Text en © Kefi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kefi, Riadh
Jeanneau, Erwann
Lefebvre, Frédéric
Ben Nasr, Cherif
Bis(2-amino-1,3-benzothia­zol-3-ium) tetra­chloridozincate(II)
title Bis(2-amino-1,3-benzothia­zol-3-ium) tetra­chloridozincate(II)
title_full Bis(2-amino-1,3-benzothia­zol-3-ium) tetra­chloridozincate(II)
title_fullStr Bis(2-amino-1,3-benzothia­zol-3-ium) tetra­chloridozincate(II)
title_full_unstemmed Bis(2-amino-1,3-benzothia­zol-3-ium) tetra­chloridozincate(II)
title_short Bis(2-amino-1,3-benzothia­zol-3-ium) tetra­chloridozincate(II)
title_sort bis(2-amino-1,3-benzothia­zol-3-ium) tetra­chloridozincate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120423/
https://www.ncbi.nlm.nih.gov/pubmed/21754568
http://dx.doi.org/10.1107/S1600536811015753
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AT bennasrcherif bis2amino13benzothiazol3iumtetrachloridozincateii

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