trans-Bis{1-[2-(2,6-diisopropyl­anilino)phenyl]-3-isopropyl­imidazolin-2-ylidenyl-κC (2)}diiodidopalladium(II) benzene disolvate

In the title complex, [PdI(2)(C(24)H(31)N(3))(2)]·2C(6)H(6), the Pd(2+) ion is located on an inversion centre in a slightly distorted square-planar geometry. The angle between the I(2)C(2) square plane and the mean plane of the N-heterocyclic carbene ring is 79.8 (2)°, with I—Pd—C—N torsion angles o...

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Detalles Bibliográficos
Autores principales: Daly, Christopher G., Singh, Kuldip, Cross, Warren B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120432/
https://www.ncbi.nlm.nih.gov/pubmed/21754579
http://dx.doi.org/10.1107/S1600536811015431
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author Daly, Christopher G.
Singh, Kuldip
Cross, Warren B.
author_facet Daly, Christopher G.
Singh, Kuldip
Cross, Warren B.
author_sort Daly, Christopher G.
collection PubMed
description In the title complex, [PdI(2)(C(24)H(31)N(3))(2)]·2C(6)H(6), the Pd(2+) ion is located on an inversion centre in a slightly distorted square-planar geometry. The angle between the I(2)C(2) square plane and the mean plane of the N-heterocyclic carbene ring is 79.8 (2)°, with I—Pd—C—N torsion angles of −81.1 (6) and −78.2 (5)°. The Pd—carbene and Pd—I distances are 2.016 (6) and 2.5971 (10) Å, respectively.
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spelling pubmed-31204322011-07-13 trans-Bis{1-[2-(2,6-diisopropyl­anilino)phenyl]-3-isopropyl­imidazolin-2-ylidenyl-κC (2)}diiodidopalladium(II) benzene disolvate Daly, Christopher G. Singh, Kuldip Cross, Warren B. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [PdI(2)(C(24)H(31)N(3))(2)]·2C(6)H(6), the Pd(2+) ion is located on an inversion centre in a slightly distorted square-planar geometry. The angle between the I(2)C(2) square plane and the mean plane of the N-heterocyclic carbene ring is 79.8 (2)°, with I—Pd—C—N torsion angles of −81.1 (6) and −78.2 (5)°. The Pd—carbene and Pd—I distances are 2.016 (6) and 2.5971 (10) Å, respectively. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120432/ /pubmed/21754579 http://dx.doi.org/10.1107/S1600536811015431 Text en © Daly et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Daly, Christopher G.
Singh, Kuldip
Cross, Warren B.
trans-Bis{1-[2-(2,6-diisopropyl­anilino)phenyl]-3-isopropyl­imidazolin-2-ylidenyl-κC (2)}diiodidopalladium(II) benzene disolvate
title trans-Bis{1-[2-(2,6-diisopropyl­anilino)phenyl]-3-isopropyl­imidazolin-2-ylidenyl-κC (2)}diiodidopalladium(II) benzene disolvate
title_full trans-Bis{1-[2-(2,6-diisopropyl­anilino)phenyl]-3-isopropyl­imidazolin-2-ylidenyl-κC (2)}diiodidopalladium(II) benzene disolvate
title_fullStr trans-Bis{1-[2-(2,6-diisopropyl­anilino)phenyl]-3-isopropyl­imidazolin-2-ylidenyl-κC (2)}diiodidopalladium(II) benzene disolvate
title_full_unstemmed trans-Bis{1-[2-(2,6-diisopropyl­anilino)phenyl]-3-isopropyl­imidazolin-2-ylidenyl-κC (2)}diiodidopalladium(II) benzene disolvate
title_short trans-Bis{1-[2-(2,6-diisopropyl­anilino)phenyl]-3-isopropyl­imidazolin-2-ylidenyl-κC (2)}diiodidopalladium(II) benzene disolvate
title_sort trans-bis{1-[2-(2,6-diisopropyl­anilino)phenyl]-3-isopropyl­imidazolin-2-ylidenyl-κc (2)}diiodidopalladium(ii) benzene disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120432/
https://www.ncbi.nlm.nih.gov/pubmed/21754579
http://dx.doi.org/10.1107/S1600536811015431
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AT singhkuldip transbis1226diisopropylanilinophenyl3isopropylimidazolin2ylidenylkc2diiodidopalladiumiibenzenedisolvate
AT crosswarrenb transbis1226diisopropylanilinophenyl3isopropylimidazolin2ylidenylkc2diiodidopalladiumiibenzenedisolvate

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