(N,N-Diethyl­nicotinamide-κN (1))bis­[4,4,4-trifluoro-1-(thien-2-yl)butane-1,3-dionato-κ(2) O,O′]copper(II)

In the title compound, [Cu(C(8)H(4)F(3)O(2)S)(2)(C(10)H(14)N(2)O)], the Cu(II) atom exists in a distorted CuNO(4) square-pyramidal geometry; the metal atom lies above a square plane defined by four O atoms of the two chelating anionic ligands, displaced in the direction of the axial occupant, the py...

Descripción completa

Detalles Bibliográficos
Autores principales: Maharramov, Abel M., Mardanova, Vusala I., Chyraqov, Famil, Gurbanov, Atash V., Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120436/
https://www.ncbi.nlm.nih.gov/pubmed/21754609
http://dx.doi.org/10.1107/S1600536811014401
_version_ 1782206678937108480
author Maharramov, Abel M.
Mardanova, Vusala I.
Chyraqov, Famil
Gurbanov, Atash V.
Ng, Seik Weng
author_facet Maharramov, Abel M.
Mardanova, Vusala I.
Chyraqov, Famil
Gurbanov, Atash V.
Ng, Seik Weng
author_sort Maharramov, Abel M.
collection PubMed
description In the title compound, [Cu(C(8)H(4)F(3)O(2)S)(2)(C(10)H(14)N(2)O)], the Cu(II) atom exists in a distorted CuNO(4) square-pyramidal geometry; the metal atom lies above a square plane defined by four O atoms of the two chelating anionic ligands, displaced in the direction of the axial occupant, the pyridine N atom, by 0.179 (1) Å. Weak inter­molecular C—H⋯O and C—H⋯F hydrogen bonding is present in the crystal structure. One thienyl ring is disordered over two orientations in an occupancy ratio of 0.69 (1):0.31.
format Online
Article
Text
id pubmed-3120436
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-31204362011-07-13 (N,N-Diethyl­nicotinamide-κN (1))bis­[4,4,4-trifluoro-1-(thien-2-yl)butane-1,3-dionato-κ(2) O,O′]copper(II) Maharramov, Abel M. Mardanova, Vusala I. Chyraqov, Famil Gurbanov, Atash V. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(8)H(4)F(3)O(2)S)(2)(C(10)H(14)N(2)O)], the Cu(II) atom exists in a distorted CuNO(4) square-pyramidal geometry; the metal atom lies above a square plane defined by four O atoms of the two chelating anionic ligands, displaced in the direction of the axial occupant, the pyridine N atom, by 0.179 (1) Å. Weak inter­molecular C—H⋯O and C—H⋯F hydrogen bonding is present in the crystal structure. One thienyl ring is disordered over two orientations in an occupancy ratio of 0.69 (1):0.31. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120436/ /pubmed/21754609 http://dx.doi.org/10.1107/S1600536811014401 Text en © Maharramov et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Maharramov, Abel M.
Mardanova, Vusala I.
Chyraqov, Famil
Gurbanov, Atash V.
Ng, Seik Weng
(N,N-Diethyl­nicotinamide-κN (1))bis­[4,4,4-trifluoro-1-(thien-2-yl)butane-1,3-dionato-κ(2) O,O′]copper(II)
title (N,N-Diethyl­nicotinamide-κN (1))bis­[4,4,4-trifluoro-1-(thien-2-yl)butane-1,3-dionato-κ(2) O,O′]copper(II)
title_full (N,N-Diethyl­nicotinamide-κN (1))bis­[4,4,4-trifluoro-1-(thien-2-yl)butane-1,3-dionato-κ(2) O,O′]copper(II)
title_fullStr (N,N-Diethyl­nicotinamide-κN (1))bis­[4,4,4-trifluoro-1-(thien-2-yl)butane-1,3-dionato-κ(2) O,O′]copper(II)
title_full_unstemmed (N,N-Diethyl­nicotinamide-κN (1))bis­[4,4,4-trifluoro-1-(thien-2-yl)butane-1,3-dionato-κ(2) O,O′]copper(II)
title_short (N,N-Diethyl­nicotinamide-κN (1))bis­[4,4,4-trifluoro-1-(thien-2-yl)butane-1,3-dionato-κ(2) O,O′]copper(II)
title_sort (n,n-diethyl­nicotinamide-κn (1))bis­[4,4,4-trifluoro-1-(thien-2-yl)butane-1,3-dionato-κ(2) o,o′]copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120436/
https://www.ncbi.nlm.nih.gov/pubmed/21754609
http://dx.doi.org/10.1107/S1600536811014401
work_keys_str_mv AT maharramovabelm nndiethylnicotinamidekn1bis444trifluoro1thien2ylbutane13dionatok2oocopperii
AT mardanovavusalai nndiethylnicotinamidekn1bis444trifluoro1thien2ylbutane13dionatok2oocopperii
AT chyraqovfamil nndiethylnicotinamidekn1bis444trifluoro1thien2ylbutane13dionatok2oocopperii
AT gurbanovatashv nndiethylnicotinamidekn1bis444trifluoro1thien2ylbutane13dionatok2oocopperii
AT ngseikweng nndiethylnicotinamidekn1bis444trifluoro1thien2ylbutane13dionatok2oocopperii

Ejemplares similares