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Tetraaquabis(2,6-dihydroxybenzoato-κO (1))(2,6-dihydroxybenzoato-κ(2) O (1),O (1′))gadolinium(III) dihydrate
In the title compound, [Gd(C(7)H(5)O(4))(3)(H(2)O)(4)]·2H(2)O, the Gd(III) ion shows a distorted square antiprismatic coordination formed by four aqua ligands and four O atoms from the three 2,6-dihydroxybenzoate (L) ligands. Two L ligands coordinate the Gd(III) ion in a monodentate mode, while t...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120440/ https://www.ncbi.nlm.nih.gov/pubmed/21754602 http://dx.doi.org/10.1107/S1600536811016163 |
Sumario: | In the title compound, [Gd(C(7)H(5)O(4))(3)(H(2)O)(4)]·2H(2)O, the Gd(III) ion shows a distorted square antiprismatic coordination formed by four aqua ligands and four O atoms from the three 2,6-dihydroxybenzoate (L) ligands. Two L ligands coordinate the Gd(III) ion in a monodentate mode, while the third coordinates it in a bidentate–chelating coordination mode. An extensive three-dimensional O—H⋯O hydrogen-bonding network consolidates the crystal packing. |
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