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Tetra­aqua­bis­(2,6-dihy­droxy­benzoato-κO (1))(2,6-dihy­droxy­benzoato-κ(2) O (1),O (1′))gadolinium(III) dihydrate

In the title compound, [Gd(C(7)H(5)O(4))(3)(H(2)O)(4)]·2H(2)O, the Gd(III) ion shows a distorted square anti­prismatic coordination formed by four aqua ligands and four O atoms from the three 2,6-dihy­droxy­benzoate (L) ligands. Two L ligands coordinate the Gd(III) ion in a monodentate mode, while t...

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Detalles Bibliográficos
Autores principales: Wang, Juangang, Zhang, Jun, Chen, Tiedan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120440/
https://www.ncbi.nlm.nih.gov/pubmed/21754602
http://dx.doi.org/10.1107/S1600536811016163
Descripción
Sumario:In the title compound, [Gd(C(7)H(5)O(4))(3)(H(2)O)(4)]·2H(2)O, the Gd(III) ion shows a distorted square anti­prismatic coordination formed by four aqua ligands and four O atoms from the three 2,6-dihy­droxy­benzoate (L) ligands. Two L ligands coordinate the Gd(III) ion in a monodentate mode, while the third coordinates it in a bidentate–chelating coordination mode. An extensive three-dimensional O—H⋯O hydrogen-bonding network consolidates the crystal packing.