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Tetraaquabis(2,6-dihydroxybenzoato-κO (1))(2,6-dihydroxybenzoato-κ(2) O (1),O (1′))gadolinium(III) dihydrate
In the title compound, [Gd(C(7)H(5)O(4))(3)(H(2)O)(4)]·2H(2)O, the Gd(III) ion shows a distorted square antiprismatic coordination formed by four aqua ligands and four O atoms from the three 2,6-dihydroxybenzoate (L) ligands. Two L ligands coordinate the Gd(III) ion in a monodentate mode, while t...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120440/ https://www.ncbi.nlm.nih.gov/pubmed/21754602 http://dx.doi.org/10.1107/S1600536811016163 |
| _version_ | 1782206679835738112 |
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| author | Wang, Juangang Zhang, Jun Chen, Tiedan |
| author_facet | Wang, Juangang Zhang, Jun Chen, Tiedan |
| author_sort | Wang, Juangang |
| collection | PubMed |
| description | In the title compound, [Gd(C(7)H(5)O(4))(3)(H(2)O)(4)]·2H(2)O, the Gd(III) ion shows a distorted square antiprismatic coordination formed by four aqua ligands and four O atoms from the three 2,6-dihydroxybenzoate (L) ligands. Two L ligands coordinate the Gd(III) ion in a monodentate mode, while the third coordinates it in a bidentate–chelating coordination mode. An extensive three-dimensional O—H⋯O hydrogen-bonding network consolidates the crystal packing. |
| format | Online Article Text |
| id | pubmed-3120440 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-31204402011-07-13 Tetraaquabis(2,6-dihydroxybenzoato-κO (1))(2,6-dihydroxybenzoato-κ(2) O (1),O (1′))gadolinium(III) dihydrate Wang, Juangang Zhang, Jun Chen, Tiedan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Gd(C(7)H(5)O(4))(3)(H(2)O)(4)]·2H(2)O, the Gd(III) ion shows a distorted square antiprismatic coordination formed by four aqua ligands and four O atoms from the three 2,6-dihydroxybenzoate (L) ligands. Two L ligands coordinate the Gd(III) ion in a monodentate mode, while the third coordinates it in a bidentate–chelating coordination mode. An extensive three-dimensional O—H⋯O hydrogen-bonding network consolidates the crystal packing. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120440/ /pubmed/21754602 http://dx.doi.org/10.1107/S1600536811016163 Text en © Wang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wang, Juangang Zhang, Jun Chen, Tiedan Tetraaquabis(2,6-dihydroxybenzoato-κO (1))(2,6-dihydroxybenzoato-κ(2) O (1),O (1′))gadolinium(III) dihydrate |
| title | Tetraaquabis(2,6-dihydroxybenzoato-κO
(1))(2,6-dihydroxybenzoato-κ(2)
O
(1),O
(1′))gadolinium(III) dihydrate |
| title_full | Tetraaquabis(2,6-dihydroxybenzoato-κO
(1))(2,6-dihydroxybenzoato-κ(2)
O
(1),O
(1′))gadolinium(III) dihydrate |
| title_fullStr | Tetraaquabis(2,6-dihydroxybenzoato-κO
(1))(2,6-dihydroxybenzoato-κ(2)
O
(1),O
(1′))gadolinium(III) dihydrate |
| title_full_unstemmed | Tetraaquabis(2,6-dihydroxybenzoato-κO
(1))(2,6-dihydroxybenzoato-κ(2)
O
(1),O
(1′))gadolinium(III) dihydrate |
| title_short | Tetraaquabis(2,6-dihydroxybenzoato-κO
(1))(2,6-dihydroxybenzoato-κ(2)
O
(1),O
(1′))gadolinium(III) dihydrate |
| title_sort | tetraaquabis(2,6-dihydroxybenzoato-κo
(1))(2,6-dihydroxybenzoato-κ(2)
o
(1),o
(1′))gadolinium(iii) dihydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120440/ https://www.ncbi.nlm.nih.gov/pubmed/21754602 http://dx.doi.org/10.1107/S1600536811016163 |
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