Cargando…

catena-Poly[[(2,2′-bipyridine)­manganese(II)]-μ(3)-4,4′-sulfonyl­dibenzoato]

In the title compound, [Mn(C(14)H(8)O(6)S)(C(10)H(8)N(2))](n), the Mn(II) ion is coordinated by four O atoms from three 4,4′-sulfonyl­dibenzoate (sdba) ligands and two N atoms from one 2,2′-bipyridine (2,2′-bipy) ligand in a distorted octa­hedral geometry. The manganese atoms are alternately bridged...

Descripción completa

Detalles Bibliográficos
Autores principales: Yan, Shi-Wei, Zhang, Guang-Ju, Chen, Hai-Yan, Chang, Suo-Cheng, Zhang, Fu-Tian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120441/
https://www.ncbi.nlm.nih.gov/pubmed/21754612
http://dx.doi.org/10.1107/S160053681101631X
_version_ 1782206680055939072
author Yan, Shi-Wei
Zhang, Guang-Ju
Chen, Hai-Yan
Chang, Suo-Cheng
Zhang, Fu-Tian
author_facet Yan, Shi-Wei
Zhang, Guang-Ju
Chen, Hai-Yan
Chang, Suo-Cheng
Zhang, Fu-Tian
author_sort Yan, Shi-Wei
collection PubMed
description In the title compound, [Mn(C(14)H(8)O(6)S)(C(10)H(8)N(2))](n), the Mn(II) ion is coordinated by four O atoms from three 4,4′-sulfonyl­dibenzoate (sdba) ligands and two N atoms from one 2,2′-bipyridine (2,2′-bipy) ligand in a distorted octa­hedral geometry. The manganese atoms are alternately bridged either by two sdba ligands, with an Mn⋯Mn separation of 12.284 (1) Å, or by two carboxyl­ate groups from two sdba ligands, with an Mn⋯Mn separation of 4.064 (1) Å, thus producing polymeric chains propagated in [101]. Weak inter­molecular C—H⋯O hydrogen bonds and π–π inter­actions [centroid–centroid distance of 3.730 (3) Å between the aromatic rings of neighbouring polymeric chains] further stabilize the crystal packing.
format Online
Article
Text
id pubmed-3120441
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-31204412011-07-13 catena-Poly[[(2,2′-bipyridine)­manganese(II)]-μ(3)-4,4′-sulfonyl­dibenzoato] Yan, Shi-Wei Zhang, Guang-Ju Chen, Hai-Yan Chang, Suo-Cheng Zhang, Fu-Tian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(14)H(8)O(6)S)(C(10)H(8)N(2))](n), the Mn(II) ion is coordinated by four O atoms from three 4,4′-sulfonyl­dibenzoate (sdba) ligands and two N atoms from one 2,2′-bipyridine (2,2′-bipy) ligand in a distorted octa­hedral geometry. The manganese atoms are alternately bridged either by two sdba ligands, with an Mn⋯Mn separation of 12.284 (1) Å, or by two carboxyl­ate groups from two sdba ligands, with an Mn⋯Mn separation of 4.064 (1) Å, thus producing polymeric chains propagated in [101]. Weak inter­molecular C—H⋯O hydrogen bonds and π–π inter­actions [centroid–centroid distance of 3.730 (3) Å between the aromatic rings of neighbouring polymeric chains] further stabilize the crystal packing. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120441/ /pubmed/21754612 http://dx.doi.org/10.1107/S160053681101631X Text en © Yan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yan, Shi-Wei
Zhang, Guang-Ju
Chen, Hai-Yan
Chang, Suo-Cheng
Zhang, Fu-Tian
catena-Poly[[(2,2′-bipyridine)­manganese(II)]-μ(3)-4,4′-sulfonyl­dibenzoato]
title catena-Poly[[(2,2′-bipyridine)­manganese(II)]-μ(3)-4,4′-sulfonyl­dibenzoato]
title_full catena-Poly[[(2,2′-bipyridine)­manganese(II)]-μ(3)-4,4′-sulfonyl­dibenzoato]
title_fullStr catena-Poly[[(2,2′-bipyridine)­manganese(II)]-μ(3)-4,4′-sulfonyl­dibenzoato]
title_full_unstemmed catena-Poly[[(2,2′-bipyridine)­manganese(II)]-μ(3)-4,4′-sulfonyl­dibenzoato]
title_short catena-Poly[[(2,2′-bipyridine)­manganese(II)]-μ(3)-4,4′-sulfonyl­dibenzoato]
title_sort catena-poly[[(2,2′-bipyridine)­manganese(ii)]-μ(3)-4,4′-sulfonyl­dibenzoato]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120441/
https://www.ncbi.nlm.nih.gov/pubmed/21754612
http://dx.doi.org/10.1107/S160053681101631X
work_keys_str_mv AT yanshiwei catenapoly22bipyridinemanganeseiim344sulfonyldibenzoato
AT zhangguangju catenapoly22bipyridinemanganeseiim344sulfonyldibenzoato
AT chenhaiyan catenapoly22bipyridinemanganeseiim344sulfonyldibenzoato
AT changsuocheng catenapoly22bipyridinemanganeseiim344sulfonyldibenzoato
AT zhangfutian catenapoly22bipyridinemanganeseiim344sulfonyldibenzoato