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catena-Poly[[(2,2′-bipyridine)manganese(II)]-μ(3)-4,4′-sulfonyldibenzoato]
In the title compound, [Mn(C(14)H(8)O(6)S)(C(10)H(8)N(2))](n), the Mn(II) ion is coordinated by four O atoms from three 4,4′-sulfonyldibenzoate (sdba) ligands and two N atoms from one 2,2′-bipyridine (2,2′-bipy) ligand in a distorted octahedral geometry. The manganese atoms are alternately bridged...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120441/ https://www.ncbi.nlm.nih.gov/pubmed/21754612 http://dx.doi.org/10.1107/S160053681101631X |
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author | Yan, Shi-Wei Zhang, Guang-Ju Chen, Hai-Yan Chang, Suo-Cheng Zhang, Fu-Tian |
author_facet | Yan, Shi-Wei Zhang, Guang-Ju Chen, Hai-Yan Chang, Suo-Cheng Zhang, Fu-Tian |
author_sort | Yan, Shi-Wei |
collection | PubMed |
description | In the title compound, [Mn(C(14)H(8)O(6)S)(C(10)H(8)N(2))](n), the Mn(II) ion is coordinated by four O atoms from three 4,4′-sulfonyldibenzoate (sdba) ligands and two N atoms from one 2,2′-bipyridine (2,2′-bipy) ligand in a distorted octahedral geometry. The manganese atoms are alternately bridged either by two sdba ligands, with an Mn⋯Mn separation of 12.284 (1) Å, or by two carboxylate groups from two sdba ligands, with an Mn⋯Mn separation of 4.064 (1) Å, thus producing polymeric chains propagated in [101]. Weak intermolecular C—H⋯O hydrogen bonds and π–π interactions [centroid–centroid distance of 3.730 (3) Å between the aromatic rings of neighbouring polymeric chains] further stabilize the crystal packing. |
format | Online Article Text |
id | pubmed-3120441 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31204412011-07-13 catena-Poly[[(2,2′-bipyridine)manganese(II)]-μ(3)-4,4′-sulfonyldibenzoato] Yan, Shi-Wei Zhang, Guang-Ju Chen, Hai-Yan Chang, Suo-Cheng Zhang, Fu-Tian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(14)H(8)O(6)S)(C(10)H(8)N(2))](n), the Mn(II) ion is coordinated by four O atoms from three 4,4′-sulfonyldibenzoate (sdba) ligands and two N atoms from one 2,2′-bipyridine (2,2′-bipy) ligand in a distorted octahedral geometry. The manganese atoms are alternately bridged either by two sdba ligands, with an Mn⋯Mn separation of 12.284 (1) Å, or by two carboxylate groups from two sdba ligands, with an Mn⋯Mn separation of 4.064 (1) Å, thus producing polymeric chains propagated in [101]. Weak intermolecular C—H⋯O hydrogen bonds and π–π interactions [centroid–centroid distance of 3.730 (3) Å between the aromatic rings of neighbouring polymeric chains] further stabilize the crystal packing. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120441/ /pubmed/21754612 http://dx.doi.org/10.1107/S160053681101631X Text en © Yan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yan, Shi-Wei Zhang, Guang-Ju Chen, Hai-Yan Chang, Suo-Cheng Zhang, Fu-Tian catena-Poly[[(2,2′-bipyridine)manganese(II)]-μ(3)-4,4′-sulfonyldibenzoato] |
title |
catena-Poly[[(2,2′-bipyridine)manganese(II)]-μ(3)-4,4′-sulfonyldibenzoato] |
title_full |
catena-Poly[[(2,2′-bipyridine)manganese(II)]-μ(3)-4,4′-sulfonyldibenzoato] |
title_fullStr |
catena-Poly[[(2,2′-bipyridine)manganese(II)]-μ(3)-4,4′-sulfonyldibenzoato] |
title_full_unstemmed |
catena-Poly[[(2,2′-bipyridine)manganese(II)]-μ(3)-4,4′-sulfonyldibenzoato] |
title_short |
catena-Poly[[(2,2′-bipyridine)manganese(II)]-μ(3)-4,4′-sulfonyldibenzoato] |
title_sort | catena-poly[[(2,2′-bipyridine)manganese(ii)]-μ(3)-4,4′-sulfonyldibenzoato] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120441/ https://www.ncbi.nlm.nih.gov/pubmed/21754612 http://dx.doi.org/10.1107/S160053681101631X |
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