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Bis(tetraethylammonium) bis(hydrogen l-tartrate) l-tartaric acid monohydrate
In the title compound, 2C(8)H(20)N(+)·2C(4)H(5)O(6) (−)·C(4)H(6)O(6)·H(2)O, the presence of the two tetraethylammonium cations is balanced by two hydrogen l-tartrate anions. Also present in the asymmetric unit are a molecule of l-tartaric acid and a water molecule. The various components are lin...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120442/ https://www.ncbi.nlm.nih.gov/pubmed/21754714 http://dx.doi.org/10.1107/S1600536811015479 |
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author | Rajalakshmi, M. Indirajith, R. Gopalakrishnan, R. Ramamurthi, K. Stoeckli-Evans, Helen |
author_facet | Rajalakshmi, M. Indirajith, R. Gopalakrishnan, R. Ramamurthi, K. Stoeckli-Evans, Helen |
author_sort | Rajalakshmi, M. |
collection | PubMed |
description | In the title compound, 2C(8)H(20)N(+)·2C(4)H(5)O(6) (−)·C(4)H(6)O(6)·H(2)O, the presence of the two tetraethylammonium cations is balanced by two hydrogen l-tartrate anions. Also present in the asymmetric unit are a molecule of l-tartaric acid and a water molecule. The various components are linked by O—H⋯O hydrogen bonds. In the crystal, two-dimensional networks are formed via O—H⋯O hydrogen bonds and C—H⋯O interactions involving the water molecule, the hydrogen l-tartrate anions and the l-tartaric acid molecules. These layers, which stack along [001], are separated by tetraethylammonium cations. The latter are also involved in C—H⋯O interactions with the anions and the l-tartaric acid and water molecules participating in the two-dimensional network. |
format | Online Article Text |
id | pubmed-3120442 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31204422011-07-13 Bis(tetraethylammonium) bis(hydrogen l-tartrate) l-tartaric acid monohydrate Rajalakshmi, M. Indirajith, R. Gopalakrishnan, R. Ramamurthi, K. Stoeckli-Evans, Helen Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, 2C(8)H(20)N(+)·2C(4)H(5)O(6) (−)·C(4)H(6)O(6)·H(2)O, the presence of the two tetraethylammonium cations is balanced by two hydrogen l-tartrate anions. Also present in the asymmetric unit are a molecule of l-tartaric acid and a water molecule. The various components are linked by O—H⋯O hydrogen bonds. In the crystal, two-dimensional networks are formed via O—H⋯O hydrogen bonds and C—H⋯O interactions involving the water molecule, the hydrogen l-tartrate anions and the l-tartaric acid molecules. These layers, which stack along [001], are separated by tetraethylammonium cations. The latter are also involved in C—H⋯O interactions with the anions and the l-tartaric acid and water molecules participating in the two-dimensional network. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120442/ /pubmed/21754714 http://dx.doi.org/10.1107/S1600536811015479 Text en © Rajalakshmi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Rajalakshmi, M. Indirajith, R. Gopalakrishnan, R. Ramamurthi, K. Stoeckli-Evans, Helen Bis(tetraethylammonium) bis(hydrogen l-tartrate) l-tartaric acid monohydrate |
title | Bis(tetraethylammonium) bis(hydrogen l-tartrate) l-tartaric acid monohydrate |
title_full | Bis(tetraethylammonium) bis(hydrogen l-tartrate) l-tartaric acid monohydrate |
title_fullStr | Bis(tetraethylammonium) bis(hydrogen l-tartrate) l-tartaric acid monohydrate |
title_full_unstemmed | Bis(tetraethylammonium) bis(hydrogen l-tartrate) l-tartaric acid monohydrate |
title_short | Bis(tetraethylammonium) bis(hydrogen l-tartrate) l-tartaric acid monohydrate |
title_sort | bis(tetraethylammonium) bis(hydrogen l-tartrate) l-tartaric acid monohydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120442/ https://www.ncbi.nlm.nih.gov/pubmed/21754714 http://dx.doi.org/10.1107/S1600536811015479 |
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