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Isonicotinonitrile–4-methylbenzoic acid (1/1)
The title structure, C(6)H(4)N(2)·C(8)H(8)O(2), is built up from an assembly of isonicotinonitrile and 4-methylbenzoic acid molecules and may be regarded as a co-crystal. The two planar molecules [r.m.s. deviations of 0.002 (6) and 0.0028 (11) Å, respectively] are linked by O—H⋯N and C—H⋯O hydrog...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120448/ https://www.ncbi.nlm.nih.gov/pubmed/21754913 http://dx.doi.org/10.1107/S1600536811019799 |
Sumario: | The title structure, C(6)H(4)N(2)·C(8)H(8)O(2), is built up from an assembly of isonicotinonitrile and 4-methylbenzoic acid molecules and may be regarded as a co-crystal. The two planar molecules [r.m.s. deviations of 0.002 (6) and 0.0028 (11) Å, respectively] are linked by O—H⋯N and C—H⋯O hydrogen bonds. They are nearly coplanar and only twisted from each other by a dihedral angle of 2.48 (6)°. In the crystal, the components are interconnected by slipped π–π stacking [centroid–centroid distance = 3.6797 (11), slippage = 1.304 Å] and intermolecular C—H⋯N interactions. |
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