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(Dimethyl sulfoxide-κO)(2-formylphenolato-κ(2) O,O′)[2-(2-oxidobenzylideneamino)phenolato-κ(3) O,N,O′]manganese(III)
The O-C(6)H(4)-CH=N–C(6)H(4)-O dianion of the title compound, [Mn(C(13)H(9)NO(2))(C(7)H(5)O(2))(C(2)H(6)OS)], acts as an O,N,O′-chelate to bind to the Mn(III) atom, and the three atoms constitute three points [O—Mn—O = 174.43 (11)°] of an octahedron around the metal atom. The azomethine linkage is...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120452/ https://www.ncbi.nlm.nih.gov/pubmed/21754583 http://dx.doi.org/10.1107/S1600536811015935 |