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Cholest-5-ene
The asymmetric unit of the title compound, C(27)H(46), contains two crytallographically independent cholest-5-ene molecules (A and B). In each molecule, the three six-membered rings are all in chair conformations, while the five-membered ring is in a twist conformation. The terminal isopropyl grou...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120455/ https://www.ncbi.nlm.nih.gov/pubmed/21754760 http://dx.doi.org/10.1107/S1600536811016783 |
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author | Khan, Mohd Shaheen Sulaiman, Othman Hashim, Rokiah Hemamalini, Madhukar Fun, Hoong-Kun |
author_facet | Khan, Mohd Shaheen Sulaiman, Othman Hashim, Rokiah Hemamalini, Madhukar Fun, Hoong-Kun |
author_sort | Khan, Mohd Shaheen |
collection | PubMed |
description | The asymmetric unit of the title compound, C(27)H(46), contains two crytallographically independent cholest-5-ene molecules (A and B). In each molecule, the three six-membered rings are all in chair conformations, while the five-membered ring is in a twist conformation. The terminal isopropyl group of molecule A has a (−)-gauche conformation, whereas that of molecule B has a (+)-gauche conformation. No significant intermolecular interactions are observed in the crystal structure. |
format | Online Article Text |
id | pubmed-3120455 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31204552011-07-13 Cholest-5-ene Khan, Mohd Shaheen Sulaiman, Othman Hashim, Rokiah Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(27)H(46), contains two crytallographically independent cholest-5-ene molecules (A and B). In each molecule, the three six-membered rings are all in chair conformations, while the five-membered ring is in a twist conformation. The terminal isopropyl group of molecule A has a (−)-gauche conformation, whereas that of molecule B has a (+)-gauche conformation. No significant intermolecular interactions are observed in the crystal structure. International Union of Crystallography 2011-05-11 /pmc/articles/PMC3120455/ /pubmed/21754760 http://dx.doi.org/10.1107/S1600536811016783 Text en © Khan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Khan, Mohd Shaheen Sulaiman, Othman Hashim, Rokiah Hemamalini, Madhukar Fun, Hoong-Kun Cholest-5-ene |
title | Cholest-5-ene |
title_full | Cholest-5-ene |
title_fullStr | Cholest-5-ene |
title_full_unstemmed | Cholest-5-ene |
title_short | Cholest-5-ene |
title_sort | cholest-5-ene |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120455/ https://www.ncbi.nlm.nih.gov/pubmed/21754760 http://dx.doi.org/10.1107/S1600536811016783 |
work_keys_str_mv | AT khanmohdshaheen cholest5ene AT sulaimanothman cholest5ene AT hashimrokiah cholest5ene AT hemamalinimadhukar cholest5ene AT funhoongkun cholest5ene |