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N,N′-Dibenzyl-N,N′-dimethyl-N′′-(methylsulfonyl)phosphoric triamide
In the title compound, C(17)H(24)N(3)O(3)PS, the P and the S atoms are each in a distorted tetrahedral environment and the N atoms display sp (2) character. The phosphoryl group and the NH unit are anti with respect to one another. The dihedral angle between the mean planes of the benzene rings is...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120462/ https://www.ncbi.nlm.nih.gov/pubmed/21754692 http://dx.doi.org/10.1107/S1600536811015832 |
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author | Pourayoubi, Mehrdad Sadeghi Seraji, Sepideh Bruno, Giuseppe Amiri Rudbari, Hadi |
author_facet | Pourayoubi, Mehrdad Sadeghi Seraji, Sepideh Bruno, Giuseppe Amiri Rudbari, Hadi |
author_sort | Pourayoubi, Mehrdad |
collection | PubMed |
description | In the title compound, C(17)H(24)N(3)O(3)PS, the P and the S atoms are each in a distorted tetrahedral environment and the N atoms display sp (2) character. The phosphoryl group and the NH unit are anti with respect to one another. The dihedral angle between the mean planes of the benzene rings is 31.08 (8)°. The crystal packing is stabilized by N—H⋯O hydrogen bonds, forming an extended chain parallel to the b axis. |
format | Online Article Text |
id | pubmed-3120462 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31204622011-07-13 N,N′-Dibenzyl-N,N′-dimethyl-N′′-(methylsulfonyl)phosphoric triamide Pourayoubi, Mehrdad Sadeghi Seraji, Sepideh Bruno, Giuseppe Amiri Rudbari, Hadi Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(24)N(3)O(3)PS, the P and the S atoms are each in a distorted tetrahedral environment and the N atoms display sp (2) character. The phosphoryl group and the NH unit are anti with respect to one another. The dihedral angle between the mean planes of the benzene rings is 31.08 (8)°. The crystal packing is stabilized by N—H⋯O hydrogen bonds, forming an extended chain parallel to the b axis. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120462/ /pubmed/21754692 http://dx.doi.org/10.1107/S1600536811015832 Text en © Pourayoubi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Pourayoubi, Mehrdad Sadeghi Seraji, Sepideh Bruno, Giuseppe Amiri Rudbari, Hadi N,N′-Dibenzyl-N,N′-dimethyl-N′′-(methylsulfonyl)phosphoric triamide |
title |
N,N′-Dibenzyl-N,N′-dimethyl-N′′-(methylsulfonyl)phosphoric triamide |
title_full |
N,N′-Dibenzyl-N,N′-dimethyl-N′′-(methylsulfonyl)phosphoric triamide |
title_fullStr |
N,N′-Dibenzyl-N,N′-dimethyl-N′′-(methylsulfonyl)phosphoric triamide |
title_full_unstemmed |
N,N′-Dibenzyl-N,N′-dimethyl-N′′-(methylsulfonyl)phosphoric triamide |
title_short |
N,N′-Dibenzyl-N,N′-dimethyl-N′′-(methylsulfonyl)phosphoric triamide |
title_sort | n,n′-dibenzyl-n,n′-dimethyl-n′′-(methylsulfonyl)phosphoric triamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120462/ https://www.ncbi.nlm.nih.gov/pubmed/21754692 http://dx.doi.org/10.1107/S1600536811015832 |
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