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2-Aminoterephthalic acid–4,4′-bipyridine (1/1)
The asymmetric unit of the title compound, C(10)H(8)N(2)·C(8)H(7)NO(4), contains two half-molecules, which constitute a 1:1 co-crystal. The 2-aminoterephthalic acid molecule is situated on an inversion center being disordered between two orientations in a 1:1 ratio. In the 4,4′-bipyridine molecu...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120464/ https://www.ncbi.nlm.nih.gov/pubmed/21754729 http://dx.doi.org/10.1107/S1600536811016448 |
Sumario: | The asymmetric unit of the title compound, C(10)H(8)N(2)·C(8)H(7)NO(4), contains two half-molecules, which constitute a 1:1 co-crystal. The 2-aminoterephthalic acid molecule is situated on an inversion center being disordered between two orientations in a 1:1 ratio. In the 4,4′-bipyridine molecule, which is situated on a twofold rotational axis, the two pyridine rings form a dihedral angle of 37.5 (1)°. In the crystal, molecules are held together via intermolecular N—H⋯O and O—H⋯N hydrogen bonds. The crystal packing exhibits π–π interactions between the aromatic rings with a centroid–centroid distance of 3.722 (3) Å. |
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