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2-Amino­terephthalic acid–4,4′-bipyridine (1/1)

The asymmetric unit of the title compound, C(10)H(8)N(2)·C(8)H(7)NO(4), contains two half-mol­ecules, which constitute a 1:1 co-crystal. The 2-amino­terephthalic acid mol­ecule is situated on an inversion center being disordered between two orientations in a 1:1 ratio. In the 4,4′-bipyridine mol­ecu...

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Detalles Bibliográficos
Autores principales: Xiao, Wenzhi, Xue, Ruiting, Yin, Yansheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120464/
https://www.ncbi.nlm.nih.gov/pubmed/21754729
http://dx.doi.org/10.1107/S1600536811016448
Descripción
Sumario:The asymmetric unit of the title compound, C(10)H(8)N(2)·C(8)H(7)NO(4), contains two half-mol­ecules, which constitute a 1:1 co-crystal. The 2-amino­terephthalic acid mol­ecule is situated on an inversion center being disordered between two orientations in a 1:1 ratio. In the 4,4′-bipyridine mol­ecule, which is situated on a twofold rotational axis, the two pyridine rings form a dihedral angle of 37.5 (1)°. In the crystal, mol­ecules are held together via inter­molecular N—H⋯O and O—H⋯N hydrogen bonds. The crystal packing exhibits π–π inter­actions between the aromatic rings with a centroid–centroid distance of 3.722 (3) Å.