2-Amino­terephthalic acid–4,4′-bipyridine (1/1)

The asymmetric unit of the title compound, C(10)H(8)N(2)·C(8)H(7)NO(4), contains two half-mol­ecules, which constitute a 1:1 co-crystal. The 2-amino­terephthalic acid mol­ecule is situated on an inversion center being disordered between two orientations in a 1:1 ratio. In the 4,4′-bipyridine mol­ecu...

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Detalles Bibliográficos
Autores principales: Xiao, Wenzhi, Xue, Ruiting, Yin, Yansheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120464/
https://www.ncbi.nlm.nih.gov/pubmed/21754729
http://dx.doi.org/10.1107/S1600536811016448
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author Xiao, Wenzhi
Xue, Ruiting
Yin, Yansheng
author_facet Xiao, Wenzhi
Xue, Ruiting
Yin, Yansheng
author_sort Xiao, Wenzhi
collection PubMed
description The asymmetric unit of the title compound, C(10)H(8)N(2)·C(8)H(7)NO(4), contains two half-mol­ecules, which constitute a 1:1 co-crystal. The 2-amino­terephthalic acid mol­ecule is situated on an inversion center being disordered between two orientations in a 1:1 ratio. In the 4,4′-bipyridine mol­ecule, which is situated on a twofold rotational axis, the two pyridine rings form a dihedral angle of 37.5 (1)°. In the crystal, mol­ecules are held together via inter­molecular N—H⋯O and O—H⋯N hydrogen bonds. The crystal packing exhibits π–π inter­actions between the aromatic rings with a centroid–centroid distance of 3.722 (3) Å.
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spelling pubmed-31204642011-07-13 2-Amino­terephthalic acid–4,4′-bipyridine (1/1) Xiao, Wenzhi Xue, Ruiting Yin, Yansheng Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(10)H(8)N(2)·C(8)H(7)NO(4), contains two half-mol­ecules, which constitute a 1:1 co-crystal. The 2-amino­terephthalic acid mol­ecule is situated on an inversion center being disordered between two orientations in a 1:1 ratio. In the 4,4′-bipyridine mol­ecule, which is situated on a twofold rotational axis, the two pyridine rings form a dihedral angle of 37.5 (1)°. In the crystal, mol­ecules are held together via inter­molecular N—H⋯O and O—H⋯N hydrogen bonds. The crystal packing exhibits π–π inter­actions between the aromatic rings with a centroid–centroid distance of 3.722 (3) Å. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120464/ /pubmed/21754729 http://dx.doi.org/10.1107/S1600536811016448 Text en © Xiao et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Xiao, Wenzhi
Xue, Ruiting
Yin, Yansheng
2-Amino­terephthalic acid–4,4′-bipyridine (1/1)
title 2-Amino­terephthalic acid–4,4′-bipyridine (1/1)
title_full 2-Amino­terephthalic acid–4,4′-bipyridine (1/1)
title_fullStr 2-Amino­terephthalic acid–4,4′-bipyridine (1/1)
title_full_unstemmed 2-Amino­terephthalic acid–4,4′-bipyridine (1/1)
title_short 2-Amino­terephthalic acid–4,4′-bipyridine (1/1)
title_sort 2-amino­terephthalic acid–4,4′-bipyridine (1/1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120464/
https://www.ncbi.nlm.nih.gov/pubmed/21754729
http://dx.doi.org/10.1107/S1600536811016448
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AT xueruiting 2aminoterephthalicacid44bipyridine11
AT yinyansheng 2aminoterephthalicacid44bipyridine11

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