Poly[μ(3)-chlorido-μ(2)-chloridodichlorido(μ-dimethyl sulfoxide-κ(2) O:S)(dimethyl sulfoxide-κO)(μ-pyrimidine-κ(2) N:N′)­ruthenium(III)sodium]

The title complex, [NaRuCl(4)(C(4)H(4)N(2))(C(2)H(6)OS)(2)](n), is the sodium salt of monoanionic octa­hedral [Ru(III)Cl(4)(pyrimidine)(DMSO)](−) in which the sulfur-bound dimethyl sulfoxide (DMSO) and pyrimidine ligand are oriented trans to one another on the Ru(III) atom. The average of the four R...

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Autores principales: Ferrara, Skylar, Kreider-Mueller, Ava, Tanski, Joseph M., Anderson, Craig M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120471/
https://www.ncbi.nlm.nih.gov/pubmed/21754645
http://dx.doi.org/10.1107/S1600536811017211
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author Ferrara, Skylar
Kreider-Mueller, Ava
Tanski, Joseph M.
Anderson, Craig M.
author_facet Ferrara, Skylar
Kreider-Mueller, Ava
Tanski, Joseph M.
Anderson, Craig M.
author_sort Ferrara, Skylar
collection PubMed
description The title complex, [NaRuCl(4)(C(4)H(4)N(2))(C(2)H(6)OS)(2)](n), is the sodium salt of monoanionic octa­hedral [Ru(III)Cl(4)(pyrimidine)(DMSO)](−) in which the sulfur-bound dimethyl sulfoxide (DMSO) and pyrimidine ligand are oriented trans to one another on the Ru(III) atom. The average of the four Ru—Cl bond lengths is 2.355 (15) Å, and the Ru—S and Ru—N bond lengths are 2.2853 (3) and 2.1165 (11) Å, respectively. The complex forms a chain, with a six-coordinate sodium ion bridging the ruthenium(III) units. The sodium cation is coordinated by cis-chloride ligands on ruthenium [Na—Cl = 2.9576 (7) and 2.6988 (7) Å], chloride and DMSO ligands from the ruthenium complexes related by inversion [Na—Cl and Na—O = 2.8888 (7) and 2.2623 (12) Å, respectively], a nitro­gen ligand from the pyrimidine of the tetrachlorido­ruthenium(III) complex related by the twofold rotation axis [Na—N = 2.5224 (14) Å] and an oxygen-bound DMSO [Na—O = 2.3165 (12) Å].
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spelling pubmed-31204712011-07-13 Poly[μ(3)-chlorido-μ(2)-chloridodichlorido(μ-dimethyl sulfoxide-κ(2) O:S)(dimethyl sulfoxide-κO)(μ-pyrimidine-κ(2) N:N′)­ruthenium(III)sodium] Ferrara, Skylar Kreider-Mueller, Ava Tanski, Joseph M. Anderson, Craig M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [NaRuCl(4)(C(4)H(4)N(2))(C(2)H(6)OS)(2)](n), is the sodium salt of monoanionic octa­hedral [Ru(III)Cl(4)(pyrimidine)(DMSO)](−) in which the sulfur-bound dimethyl sulfoxide (DMSO) and pyrimidine ligand are oriented trans to one another on the Ru(III) atom. The average of the four Ru—Cl bond lengths is 2.355 (15) Å, and the Ru—S and Ru—N bond lengths are 2.2853 (3) and 2.1165 (11) Å, respectively. The complex forms a chain, with a six-coordinate sodium ion bridging the ruthenium(III) units. The sodium cation is coordinated by cis-chloride ligands on ruthenium [Na—Cl = 2.9576 (7) and 2.6988 (7) Å], chloride and DMSO ligands from the ruthenium complexes related by inversion [Na—Cl and Na—O = 2.8888 (7) and 2.2623 (12) Å, respectively], a nitro­gen ligand from the pyrimidine of the tetrachlorido­ruthenium(III) complex related by the twofold rotation axis [Na—N = 2.5224 (14) Å] and an oxygen-bound DMSO [Na—O = 2.3165 (12) Å]. International Union of Crystallography 2011-05-14 /pmc/articles/PMC3120471/ /pubmed/21754645 http://dx.doi.org/10.1107/S1600536811017211 Text en © Ferrara et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ferrara, Skylar
Kreider-Mueller, Ava
Tanski, Joseph M.
Anderson, Craig M.
Poly[μ(3)-chlorido-μ(2)-chloridodichlorido(μ-dimethyl sulfoxide-κ(2) O:S)(dimethyl sulfoxide-κO)(μ-pyrimidine-κ(2) N:N′)­ruthenium(III)sodium]
title Poly[μ(3)-chlorido-μ(2)-chloridodichlorido(μ-dimethyl sulfoxide-κ(2) O:S)(dimethyl sulfoxide-κO)(μ-pyrimidine-κ(2) N:N′)­ruthenium(III)sodium]
title_full Poly[μ(3)-chlorido-μ(2)-chloridodichlorido(μ-dimethyl sulfoxide-κ(2) O:S)(dimethyl sulfoxide-κO)(μ-pyrimidine-κ(2) N:N′)­ruthenium(III)sodium]
title_fullStr Poly[μ(3)-chlorido-μ(2)-chloridodichlorido(μ-dimethyl sulfoxide-κ(2) O:S)(dimethyl sulfoxide-κO)(μ-pyrimidine-κ(2) N:N′)­ruthenium(III)sodium]
title_full_unstemmed Poly[μ(3)-chlorido-μ(2)-chloridodichlorido(μ-dimethyl sulfoxide-κ(2) O:S)(dimethyl sulfoxide-κO)(μ-pyrimidine-κ(2) N:N′)­ruthenium(III)sodium]
title_short Poly[μ(3)-chlorido-μ(2)-chloridodichlorido(μ-dimethyl sulfoxide-κ(2) O:S)(dimethyl sulfoxide-κO)(μ-pyrimidine-κ(2) N:N′)­ruthenium(III)sodium]
title_sort poly[μ(3)-chlorido-μ(2)-chloridodichlorido(μ-dimethyl sulfoxide-κ(2) o:s)(dimethyl sulfoxide-κo)(μ-pyrimidine-κ(2) n:n′)­ruthenium(iii)sodium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120471/
https://www.ncbi.nlm.nih.gov/pubmed/21754645
http://dx.doi.org/10.1107/S1600536811017211
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