(E,E,E,E)-2,3,5,6-Tetra­kis{2-[4-(dimethyl­amino)­phen­yl]ethen­yl}pyrazine

In the title compound, C(44)H(48)N(6), the essentially planar mol­ecule [maximum deviation from the mean plane of the π system of 0.271 (3) Å] is located on a crystallographic centre of inversion. The almost planar (angle sums at N atoms = 357.6 and 357.1°) dimethyl­amino groups and short C—N bonds...

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Detalles Bibliográficos
Autores principales: Schmitt, Volker, Schollmeyer, Dieter, Detert, Heiner
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120474/
https://www.ncbi.nlm.nih.gov/pubmed/21754911
http://dx.doi.org/10.1107/S1600536811019714
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author Schmitt, Volker
Schollmeyer, Dieter
Detert, Heiner
author_facet Schmitt, Volker
Schollmeyer, Dieter
Detert, Heiner
author_sort Schmitt, Volker
collection PubMed
description In the title compound, C(44)H(48)N(6), the essentially planar mol­ecule [maximum deviation from the mean plane of the π system of 0.271 (3) Å] is located on a crystallographic centre of inversion. The almost planar (angle sums at N atoms = 357.6 and 357.1°) dimethyl­amino groups and short C—N bonds of the aniline groups [both 1.379 (4) Å] indicate strong electronic coupling between these groups and the central pyrazine ring.
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spelling pubmed-31204742011-07-13 (E,E,E,E)-2,3,5,6-Tetra­kis{2-[4-(dimethyl­amino)­phen­yl]ethen­yl}pyrazine Schmitt, Volker Schollmeyer, Dieter Detert, Heiner Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(44)H(48)N(6), the essentially planar mol­ecule [maximum deviation from the mean plane of the π system of 0.271 (3) Å] is located on a crystallographic centre of inversion. The almost planar (angle sums at N atoms = 357.6 and 357.1°) dimethyl­amino groups and short C—N bonds of the aniline groups [both 1.379 (4) Å] indicate strong electronic coupling between these groups and the central pyrazine ring. International Union of Crystallography 2011-05-28 /pmc/articles/PMC3120474/ /pubmed/21754911 http://dx.doi.org/10.1107/S1600536811019714 Text en © Schmitt et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Schmitt, Volker
Schollmeyer, Dieter
Detert, Heiner
(E,E,E,E)-2,3,5,6-Tetra­kis{2-[4-(dimethyl­amino)­phen­yl]ethen­yl}pyrazine
title (E,E,E,E)-2,3,5,6-Tetra­kis{2-[4-(dimethyl­amino)­phen­yl]ethen­yl}pyrazine
title_full (E,E,E,E)-2,3,5,6-Tetra­kis{2-[4-(dimethyl­amino)­phen­yl]ethen­yl}pyrazine
title_fullStr (E,E,E,E)-2,3,5,6-Tetra­kis{2-[4-(dimethyl­amino)­phen­yl]ethen­yl}pyrazine
title_full_unstemmed (E,E,E,E)-2,3,5,6-Tetra­kis{2-[4-(dimethyl­amino)­phen­yl]ethen­yl}pyrazine
title_short (E,E,E,E)-2,3,5,6-Tetra­kis{2-[4-(dimethyl­amino)­phen­yl]ethen­yl}pyrazine
title_sort (e,e,e,e)-2,3,5,6-tetra­kis{2-[4-(dimethyl­amino)­phen­yl]ethen­yl}pyrazine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120474/
https://www.ncbi.nlm.nih.gov/pubmed/21754911
http://dx.doi.org/10.1107/S1600536811019714
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