N-(Pyridin-2-ylmeth­yl)pyridin-2-amine

The title compound, C(11)H(11)N(3), crystallizes with two mol­ecules (A and B) in the asymmetric unit. The geometries of both mol­ecules are very similar, with the exception of the torsion angles of the inter-ring chains; the values for C—N—C—C are 67.4 (5) and −69.3 (5)° for mol­ecules A and B, res...

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Detalles Bibliográficos
Autores principales: Moon, Suk-Hee, Kim, Tae Ho, Park, Ki-Min
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120475/
https://www.ncbi.nlm.nih.gov/pubmed/21754749
http://dx.doi.org/10.1107/S1600536811016874
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author Moon, Suk-Hee
Kim, Tae Ho
Park, Ki-Min
author_facet Moon, Suk-Hee
Kim, Tae Ho
Park, Ki-Min
author_sort Moon, Suk-Hee
collection PubMed
description The title compound, C(11)H(11)N(3), crystallizes with two mol­ecules (A and B) in the asymmetric unit. The geometries of both mol­ecules are very similar, with the exception of the torsion angles of the inter-ring chains; the values for C—N—C—C are 67.4 (5) and −69.3 (5)° for mol­ecules A and B, respectively. The dihedral angles between the pyridyl ring planes are 84.0 (2) and 83.2 (2)° for mol­ecules A and B, respectively. In the crystal, weak inter­molecular N—H⋯N hydrogen bonds and C—H⋯π inter­actions contribute to the stabilization of the packing.
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spelling pubmed-31204752011-07-13 N-(Pyridin-2-ylmeth­yl)pyridin-2-amine Moon, Suk-Hee Kim, Tae Ho Park, Ki-Min Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(11)H(11)N(3), crystallizes with two mol­ecules (A and B) in the asymmetric unit. The geometries of both mol­ecules are very similar, with the exception of the torsion angles of the inter-ring chains; the values for C—N—C—C are 67.4 (5) and −69.3 (5)° for mol­ecules A and B, respectively. The dihedral angles between the pyridyl ring planes are 84.0 (2) and 83.2 (2)° for mol­ecules A and B, respectively. In the crystal, weak inter­molecular N—H⋯N hydrogen bonds and C—H⋯π inter­actions contribute to the stabilization of the packing. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120475/ /pubmed/21754749 http://dx.doi.org/10.1107/S1600536811016874 Text en © Moon et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Moon, Suk-Hee
Kim, Tae Ho
Park, Ki-Min
N-(Pyridin-2-ylmeth­yl)pyridin-2-amine
title N-(Pyridin-2-ylmeth­yl)pyridin-2-amine
title_full N-(Pyridin-2-ylmeth­yl)pyridin-2-amine
title_fullStr N-(Pyridin-2-ylmeth­yl)pyridin-2-amine
title_full_unstemmed N-(Pyridin-2-ylmeth­yl)pyridin-2-amine
title_short N-(Pyridin-2-ylmeth­yl)pyridin-2-amine
title_sort n-(pyridin-2-ylmeth­yl)pyridin-2-amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120475/
https://www.ncbi.nlm.nih.gov/pubmed/21754749
http://dx.doi.org/10.1107/S1600536811016874
work_keys_str_mv AT moonsukhee npyridin2ylmethylpyridin2amine
AT kimtaeho npyridin2ylmethylpyridin2amine
AT parkkimin npyridin2ylmethylpyridin2amine

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